Reaction of 2-X-N-methylbenzimidazole (X = chloro, iodo) with Ni(0) complexes in the presence of dppe or PEt(3) and an external proton source yielded via an oxidative addition reaction nickel(II) complexes bearing NH,NMe-functionalized NHC ligands.

Complexes of the diuretic benzothiadiazine derivative chlorothiazide (6-chloro-7-sulfamoyl- 1,2,4-benzothiadiazine-1,1-dioxide) with V(IV); Fe(II); Co(II); Ni(II); Cu(II), Ag(I) and U(VI) were prepared and characterized by elemental analysis, spectroscopic, thermogravimetric, magnetic and conductimetric measurements. The complexes behave as effective inhibitors for two isozymes (I and II) of ca...

In this work, we report the electrochemical response of a family Co(II) complexes, [CoII(L)3]2+ and [CoII(L’)2]2+ (L = 2,2’-bipyridine, 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline, 5,6-dimethyl-1,10-phenanthroline, 4,7-diphenyl-1,10-phenanthroline; L’ terpyridine 4-chloro-terpyridine), in presence absence CO2 order to understand role redox potential molecular structure on catal...

The mixed-ligand complexes of various metal(II) with 5-chloro-7-iodo-8-hydroxyquinoline (Clioquinol) and 5-(methoxymethyl-8-quinolinol) (MMQ) were prepared. The structure of mixed-ligand complexes was investigated using spectral, physicochemical, elemental analyses and thermal studies. Magnetic moment and reflectance spectral studies reveal that an octahedral geometry has been assigned to all t...