نتایج جستجو برای: lacoo3

تعداد نتایج: 204  

Journal: :Physical chemistry chemical physics : PCCP 2014
T Poux A Bonnefont A Ryabova G Kéranguéven G A Tsirlina E R Savinova

Hydrogen peroxide has been identified as a stable intermediate of the electrochemical oxygen reduction reaction on various electrodes including metal, metal oxide and carbon materials. In this article we study the hydrogen peroxide oxidation and reduction reactions in alkaline medium using a rotating disc electrode (RDE) method on oxides of the perovskite family (LaCoO3, LaMnO3 and La0.8Sr0.2Mn...

Journal: :Physical review letters 2013
P Augustinský V Křápek J Kuneš

Hole and electron doped LaCoO3 is studied using dynamical mean-field theory. The one-particle spectra are analyzed and compared to the available experimental data, in particular the x-ray absorption spectra. Analyzing the temporal spin-spin correlation functions we find the atomic intermediate spin state is not important for the observed Curie-Weiss susceptibility. Contrary to the commonly held...

Journal: :Physical review letters 2006
D Phelan Despina Louca S Rosenkranz S-H Lee Y Qiu P J Chupas R Osborn H Zheng J F Mitchell J R D Copley J L Sarrao Y Moritomo

Inelastic cold-neutron scattering on LaCoO3 provided evidence for a distinct low energy excitation at 0.6 meV coincident with the thermally induced magnetic transition. Coexisting strong ferromagnetic (FM) and weaker antiferromagnetic correlations that are dynamic follow the activation to the excited state, identified as the intermediate S = 1 spin triplet. This is indicative of dynamical orbit...

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