this paper deals with a theoretical mathematical analysis of one-dimensional solidification problem, in which kinetic undercooling is incorporated into the this temperature condition at the interface. a model problem with nonlinear kinetic law is considered. we prove a local result intimate for the uniqueness of solution of the corresponding free boundary problem.

the effective removal of dyes from aqueous wastewaters is among the most important issues formany industrialized countries. removal of congo red (cr) dye from aqueous solutions was studiedusing nickel oxide nanoparticles. the operating variables studied were initial ph of solution,adsorbents dosage, temperature and contact time. the morphological information of nickel oxidenanoparticles were ch...

in this study, bimodal meso-porous silica (uvm-7) synthesized and fabricated amino silane modified supports were characterized by powder x-ray diffraction (xrd), n2 adsorption/desorption, transmission electron microscope (tem), elemental analysis and titration. capacity of co2 capture on modified bimodal pore structure silica at 70°c was calculated using breakthrough curves; and it was found th...

the objective of this study was to assess the potential of cadmium sulfide nanoparticles loaded onto activated carbon (cdsn-ac) for the removal of sunset yellow (sy) dye from aqueous solution. adsorption studies were conducted in a batch mode varying solution ph, contact time, initial dye concentration, cdsn-ac dose. in order to investigate the efficiency of sy adsorption on cdsn-ac, pseudo-fir...

Coming out from the growth kinetics, the Gompertz model has been developed and considered as the best one for simulating the biogas production from anaerobic digestion. However, the model has failed to describe the starting point of the process, and no-sense of lag phase constant has been pointed out. Thus, the goal of this study is to develop a new kinetic model of biogas production with meani...

Reaction furnace is the most important part of the Claus sulfur recovery unit and its performance has a significant impact on the process efficiency. Too many reactions happen in the furnace and their kinetics and mechanisms are not completely understood; therefore, modeling reaction furnace is difficult and several works have been carried out on in this regard so far. Equilibrium models are co...

in this study, decolorization of the diazo dye, reactive black 5 (rb5) in a coprinus cinereus peroxidase-catalyzed reaction has been investigated. a bisubstate kinetic model for the reaction rate based on the ping-pong mechanism was assumed for the enzymatic decolorization. experimentswere conducted at different rb5 and hydrogen peroxideconcentrations in a batch mannerto estimate the intrinsic ...

Kinetic modeling is an important issue, whose objective is the accurate determination of the rates of various reactions taking place in a reacting system. This issue is a pivotal element in the process design and development particularly for novel processes which are based on reactions taking place between various types of species. The Fischer Tropsch (FT) reactions have been used as the ki...

The kinetic of Fischer-Tropsch synthesis over a co-precipitated Fe-Ce catalyst was investigated in a fixed bed micro reactor. Experimental conditions were varied as follow: reaction pressure 1-15bar, H¬¬¬2/CO feed ratio of 1-3 and space velocity of 3600-5400 h-1 at the temperature range of 270-310°C. 4 models according to the Langmuir-Hinshelwood-Hougen-Watson (LHHW) type rate equation were der...

Alneact, We present a kinetic lattice system that evolves in general towards steady nonequilibrium states due to dynamical conflict between nearestand next-nearest-neighbour interactions, Under two simple particular limits, the system would reach asymptotically the canonical equi!ihium' states for the ordinary Ising model and for the axial next-nearestneighbour Ising (ANNNI) model, respectively...