The scale up of an isothermal micro-trickle bed reactor operated under radio frequency (RF) heating has been performed. The effect of the reactor length, tube diameter and number of parallel tubes on the temperature non-uniformity parameter has been studied. The axial and radial temperature profiles were calculated using a 2D convection and conduction heat transfer problem with heat transfer pr...

In this paper, a reaction system consisting of two parallel, non-isothermal autocatalytic reactions in a Continuous Stirred Tank Reactor (CSTR) has been considered. Reactor chaotic behavior is possible for certain values of system parameters. Two types of controllers are designed and compared in order to control both the reactor temperature and the product concentration. T...

This paper proposes a thermodynamical pseudo Hamiltonian formulation of Continuous Stirred Tank Reactor model in which takes place some chemical reaction. This is done both in the isothermal and non isothermal cases. It is shown that the Gibbs free energy and the opposite of entropy can be chosen as Hamiltonian function respectively. For the non isothermal case, the so called Interconnection an...

The thermal deactivation of TEM-1 β-lactamase was examined using two experimental techniques: a series of isothermal batch assays and a single, continuous, non-isothermal assay in an enzyme membrane reactor (EMR). The isothermal batch-mode technique was coupled with the three-state "Equilibrium Model" of enzyme deactivation, while the results of the EMR experiment were fitted to a four-state "m...

in a novel dual bed reactor fischer-tropsch synthesis was studied by using two diffrent cobalt catalysts. an alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a rutenuim promoted cobalt catalyst in the second bed. the activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed react...

in this paper, modeling and optimization of fischer-tropsch synthesis is considered in a fixed-bed catalytic reactor using an industrial fe-cu-k catalyst. a one dimensional pseudo-homogenous plug flow model without axial dispersion is developed for converting syngas to heavy hydrocarbons. the effects of temperature, pressure, h2 to co ratio in feed stream, and co molar flow on the mass flow rat...

This study addresses the development of a compact reactor for oxidative steam-reforming of methanol (OSRM) to produce hydrogen in autothermal mode for fuel cells. The string reactor uses catalytically active brass wires with a diameter of 500 mm placed in parallel into a tube. The micro-channels in the reactor for gases are formed between the wires presenting hydrodynamics similar to the one in...

The analysis of the potential to improve performance a methanol synthesis reactor through forced periodical operations by Nonlinear Frequency Response method is presented. in an isothermal and isobaric lab-scale CSTR considered. First, was performed for single input modulations (in Part I), which showed that significant improvements can’t be achieved. Here, study extended simultaneous two input...

Sodium borohydride (NaBH4) hydrogen storage systems offer many advantages for hydrogen storage applications. The physical processes nside a NaBH4 packed bed reactor involve multi-component and multi-phase flow and multi-mode heat and mass transfer. These processes are lso coupled with reaction kinetics. To guide reactor design and optimization, a reactor model involving all of these processes i...

-A pilot plant study on propane catalytic combustion in a membrane reactor with separate reactant feeds is presented. The membrane consisted of a porous alumina tube activated by insertion into its pores of a Pt/7-A1203 catalyst. The role of reactants concentration and of the feed flow rates were studied in the transport-controlled operating regime, where a number of interesting properties of t...