On the basis of the linked-graph expansion theorem established by one of us, it is shown that the modified F model in a small electric field is related to a two-dimensional nearest-neighbor Ising model in an external magnetic field. Applying this relation to the critical isotherm we get ~5 = 7, and confirm the scaling relation. R~sum~ Sur la base du th6or~me de d6veloppement en graphes li6s 6ta...

In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental ...

This study explored the feasibility of using granular ferric hydroxide as adsorbent for the removal of NO3-N. Optimum conditions for NO3-N removal were found to be pH 5.0 and equilibrium time 80min. The equilibrium sorption isotherm was better described by Langmuir sorption isotherm model. The maximum sorption capacity of granular ferric hydroxide was 4.254mg/g at 298K. A comparison of four kin...

The present study reports the kinetic and absorption performance of novel nanometre scale hydroxyapatite (HAP) absorber synthesised from a combined ultrasound and microwave based technique for the removal of metal ions (Fe, Cu and Zn) from aqueous solutions. After powder characterisation was carried out using XRD, SEM, EDS and FT-IR, batch adsorption studies were carried out. Kinetic studies es...

Discharge of heavy metals into aquatic ecosystems has become a matter of concern over the last few decades. The search for new technologies involving the removal of toxic metals from wastewaters has directed the attention to biosorption, based on metal binding capacities of various biological materials. Degree of sorbent affinity for the sorbate determines its distribution between the solid and...

this paper discusses the biosorption of ni(ii) ions from aqueous solutions by bacillus sphaericus biomass. the biosorption process was affected by the solution ph, biomass concentration, contact time, temperature and initial ni(ii) concentration respectively. the sorption kinetics and equilibrium data were described well with the pseudo-second order kinetic model and the freundlich isotherm mod...

in this study, nano-tio2 was employed for the adsorption of chloroform from aqueous solution in batch equilibrium experiments to investigate its adsorption properties. the effects of ph, initial chloroform concentration and nano-tio2 dosage were also investigated. optimal conditions for chloroform removal by nano-tio2 have been then identified. results of equilibrium experiments showed that the...

This paper presents the feasibility of removal of MB dye from aqueous solution using activated carbon prepared from Usoro fiber (Adenia lobata). FTIR analysis revealed that many functional groups were present on the surface of the adsorbent. The adsorption Kinetics was analyzed by pseudo first order, pseudo second order and intra particle diffusion kinetics models. Results showed that MB adsorp...

In the present work, the usefulness of almond peel as a sorbent material has been investigated for the removal of methylene blue from synthetic aqueous solutions in batch conditions. Isotherm of dye sorption was measured. The influence of different experimental parameters such as: almond peel mass, particles size, temperature, initial pH of solution and NaCl concentration on this isotherm was s...

The effect of temperature on the equilibrium sorption of Pb 2+ from aqueous solution onto a low-cost electric furnace slag was investigated. In this paper, two-parameter isotherm models namely the Langmuir and the Freundlich and three-parameter isotherm model namely Redlich–Peterson were applied to describe the isotherms and to calculate their constants. The best estimation of the parameters of...