This paper investigates the potential of pristine and acid-treated olivine as a substrate for CO2 capture using a vacuum swing adsorption (VSA) process from the gas-solid phase. The experiments tested the isotherm of pure CO2 adsorption with partial pressure from 10−5 to 1 bar at ambient temperature. The CO2 adsorption capacity and actual expected working capacity (EWC) curves of pristine and a...

We explore the detailed structure of heat release and the energy budget for a freely-propagating lean, premixed hydrogen flame. At lean conditions, the flame is thermodiffusively unstable and spontaneously develops the cellular burning structures, characteristic of this type of flame. The instabilities in the system saturate quickly, resulting in robust, slowly evolving cellular burning feature...

The transport and fate of many contaminants in subsurface systems can be influenced by several coupled processes, such as nonlinear, rate-limited sorption and biodegradation. We investigated the transport in soil of a model organic compound, 2,4-dichlorophenoxyacetic acid (2,4-D), influenced by nonlinear, rate-limited sorption and biodegradation. Miscible displacement and batch sorption experim...

[1] Seinfeld JH. Air pollution: physical and chemical fundamentals. New York: McGraw Hill; 1975. p. 1–26. [2] Arthur CS. In: Measuring, monitoring, and surveillance of air pollution, vol. 3. New York: Academic Press; 1976. p. 183–305. [3] Tseng HH, Wey MY, Liang YS, Chen KH. Catalytic removal of SO2, NO and HCl from incineration flue gas over activated carbonsupported metal oxides. Carbon 2003;...

Adsorption characteristics of potentially toxic metals in single- and multi-metal forms onto ferronickel slag were evaluated. Competitive sorption of metals by ferronickel slag has never been reported previously. The maximum adsorption capacities of toxic metals on ferronickel were in the order of Cd (10.2 mg g(-1)) > Cu (8.4 mg g(-1)) > Zn (4.4 mg g(-1)) in the single-metal adsorption isotherm...

For the first time we apply a new method based on the mathematical derivation of some known isotherm from the Burr function which describes many birth-death (sorption-desorption) phenomena in ecology and economy. Therefore, in this study the experimental isotherm data of biosorption of Pb(II) onto algae was modeled to Langmuir, Hill-Sips, Brouers-Sotolongo, BrouersGaspard, and Redlich-Peterson ...

Parameters from single-component isotherm models were used in multicomponent isotherm models to predict the aqueous phase sorption of trichloroethylene (TCE) in the presence of tetrachloroethylene (PCE) in four zeolites, Tenax, and three natural solids. The Langmuir, the Polanyi-Dubinin, and the Freundlich or the Langmuir-Freundlich isotherm models were used to simulate single-component sorptio...

ACKNOWLEDGEMENTS I would like to thank my adviser Michael Zieve for teaching me to fish. I would like to thank Jeffrey Lagarias for helpful feedback in writing this thesis. I would like to thank my family (Peter, Susan, and Holly), my beautiful girlfriend Becky, and the community of Michigan graduate students for keeping me sane.

[1] The strong jet, with a speed between 500 and 600 m/s, is inferred in the equatorial region of Saturn by combining the nadir and limb observations of Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft. A similar jet was discovered on Jupiter (F. M. Flasar et al., 2004a). These discoveries raise the possibility that intense jets are common in the equatorial stratospheres of ...