This study investigates the capacity of granular activated carbon (GAC) for the storage of methane through the equilibrium adsorption. An experimental apparatus consist of a dual adsorption vessel was set up for the measurement of equilibrium adsorption of methane on GAC using volumetric technique (pressure decay). Experimental isotherms of methane adsorption were determined by the measurement ...

The effect of temperature on the equilibrium sorption of Pb 2+ from aqueous solution onto a low-cost electric furnace slag was investigated. In this paper, two-parameter isotherm models namely the Langmuir and the Freundlich and three-parameter isotherm model namely Redlich–Peterson were applied to describe the isotherms and to calculate their constants. The best estimation of the parameters of...

The present work investigates the equilibrium adsorption of Chrysene on multi-walled carbon nanotubes at 293, 303 and 313°K, and determines the equilibrium adsorption isotherms and thermodynamic parameters (ΔG, ΔH and ΔS). The values of ΔH and ΔG suggested that the adsorption of Chrysene onto MWCNTs was endothermic and nonspontaneous.The experimental data were analyzed using Langmuir, Freundlic...

We calculated the inherent structure of a model melt of zinc ~II! bromide over a wide range of densities. Stable, metastable, and unstable branches were obtained for the zero temperature pressure–volume isotherm of the inherent structure. The pressure–volume isotherm, the void distribution, and the structure factor were used to identify the spinodal, independent of any model equation of state. ...

By allowing the surface charge of one surface to affect the adsorption equilibrium of the other, we establish the existence of a long-range attractive interaction between two identical surfaces in an electrolyte containing polyvalent counterions with a mean-field Poisson-Boltzmann approach. A Stern electrostatic condition from linearization of the mass-action adsorption isotherm is used to capt...

The potential use of Croatian natural zeolite clinoptilolite as alternative adsorbents for removal of enrofloxacin (ENRO) as model pollutant was studied in a batch system. The influence of contact time and initial ENRO concentration on the sorption process was investigated. The percentage removal of ENRO from aqueous phase decreased with an increase in initial concentration. The experimental da...

Beet discs aged in 0.5 mM CaSO(4) develop a capacity to absorb K(+) and Cl(-) from solutions of low concentration. The initial influx of these ions is described by a hyperbolic relationship with concentration in the range 0.01 to 0.5 mM KCl, which is identical with the system 1 absorption isotherm found in other tissues. A second hyperbolic isotherm, attributable to system 2, is found at higher...

Few studies have combined molecular- and macroscopic-scale investigations with surface complexation model (SCM) development to predict trace metal speciation and partitioning in aqueous systems over a broad range of conditions. In this work, an extensive collection of new macroscopic and spectroscopic data was used to assess the ability of the modified triple-layer model (TLM) to predict single...

In the present study, activated carbons of Eichornea crasssipes(EC), Sugarcane bagassae(SB), Tea waste(TW) and Guava leaf(GL) were prepared from agricultural wastes and used as an adsorbents for the removal of Acid Blue 92 (AB92) dye from aqueous solution. The effects of pH, adsorbent dosage, initial dye concentration and contact time on the extent removal of AB92 has been studied by Batch adso...

Development of quantitative theory of adsorption-induced deformation is important, e.g., for enhanced coalbed methane recovery by CO2 injection. It is also promising for the interpretation of experimental measurements of elastic properties of porous solids. We study deformation of mesoporous silica by n-pentane adsorption. The shape of experimental strain isotherms for this system differs from ...