نتایج جستجو برای: isatin β thiosemicarbazone

تعداد نتایج: 179088  

2012
VINIT RAJ

Isatin derivatives are one of most potent anticonvulsant agent of natural origin. It has display potent anticonvulsant effect in a wide variety of preclinical anticonvulsant models. Till date various isatin derivatives have been synthesized and evaluated for anticonvulsant activity. This review is an attempt to compile the medicinal chemistry of various synthesized isatin analogs. Isatin and it...

Journal: :Organic & biomolecular chemistry 2013
Likai Xia Yong Rok Lee

We describe an efficient one-step synthesis of pyrrolo[3,4-c]quinolinedione derivatives using ethylenediamine diacetate (EDDA)-catalyzed cascade reactions of isatins and β-ketoamides. It is the first direct conversion of isatins to pyrrolo[3,4-c]quinolinedione derivatives via C-N bond cleavage and isatin ring expansion. Furthermore, this reaction provides a one-step synthetic route for the prod...

Journal: :Dalton transactions 2015
Muneebah Adams Carmen de Kock Peter J Smith Kirkwood M Land Nicole Liu Melissa Hopper Allyson Hsiao Andrew R Burgoyne Tameryn Stringer Mervin Meyer Lubbe Wiesner Kelly Chibale Gregory S Smith

A series of ferrocenyl- and aryl-functionalised organosilane thiosemicarbazone compounds was obtained via a nucleophilic substitution reaction with an amine-terminated organosilane. The thiosemicarbazone (TSC) ligands were further reacted with either a ruthenium dimer [(η(6-i)PrC6H4Me)Ru(μ-Cl)Cl]2 or a rhodium dimer [(Cp*)Rh(μ-Cl)Cl]2 to yield a series of cationic mono- and binuclear complexes....

Journal: :Molecules 2017
Giulia Rainoldi Matteo Faltracco Claudia Spatti Alessandra Silvani Giordano Lesma

This work describes the synthesis of enantioenriched spiro compounds, incorporating the azetidine and the oxindole motifs. The preparation relies on a formal [2 + 2] annulation reaction of isatin-derived N-tert-butylsulfonyl ketimines with allenoates. The asymmetric induction is secured by an organocatalytic strategy, exploiting a bifunctional cinchona-type β-isocupridine-based catalyst. Some p...

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