a total of 148 groundwater samples were collected from bore wells from thirumanimuttar sub-basin for two seasons to identify major geochemical process activated to alter groundwater chemistry. the study revealed relationships with the lithology and anthropogenic process. groundwater in the region was dominated by na – ca – mg and cl and hco3 types. the (ca +mg) versus tz+ plot for both seas...

In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...

Previous studies have indicated that the deposition of uranium in bone is a surface-limited reaction involving an exchange of the uranyl ions of the solution for some ion in the surface of the mineral phase of bone, probably calcium (1, 2). As a further test of the exchange hypothesis, a series of ion competition experiments was conducted, in which the effects of varying concentrations of hydro...

The transport properties of various anion and cation exchange membranes were studied in different electrolyte solutions using chronopotentiometry technique to get insight about the influence of the counter ion on the transport properties of the membranes. The investigated samples include heterogeneous ion exchange membranes varying in the functionality of fixed charged gro...

Ion-exclusion chromatography (IEC) has been widely used in the separation of carboxylic acids, finding applications in the analysis of food and beverages, pharmaceuticals, biological samples, and acid rain samples.' The retention mechanism of carboxylic acids in ion-exclusion chromatography has also been investigated in many studies, and the factors which affect retention can be divided into th...

Ion-exclusion chromatography (IEC) has been widely used in the separation of carboxylic acids, finding applications in the analysis of food and beverages, pharmaceuticals, biological samples, and acid rain samples.1 The retention mechanism of carboxylic acids in ion-exclusion chromatography has also been investigated in many studies, and the factors which affect retention can be divided into th...

In this study, we compare the separation of basic drugs on several octadecyl silane bonded silica (ODS) phases and a polybutadiene-coated zirconia (PBD–ZrO ) phase. The retention characteristics were investigated in detail using a variety of 2 cationic drugs as probe solutes. The ODS phases were selected to cover a relatively wide range in silanol activity and were studied with ammonium phospha...

a pvc-based membrane containing cerium phosphate was developed. unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. the response of molybdate selective electrode based on this membrane was perfectly linear in the concentratio...

A novel counter-ion, N-methylimipramine, was synthesized and utilized in the separation of inositol phosphates by ion-pair chromatography. The structural identity of the counter-ion was documented by nuclear magnetic resonance spectroscopy. This counter-ion was capable of resolving inositol phosphates isocratically by reversed-phase high-performance liquid chromatography. Solvent polarity and i...

nitrate is an anion of major importance particularly in biological areas. excessive amounts in water supplies indicate pollution from sewage or agricultural effluents. the effects of excessive quantities of nitrate in water are well known. in this research structural modification of natural clinoptilolite by isomorphic substitution was performed. isomorphously substituted zeolite was prepared u...