The nanostructured Ce ion substituted cryptomelane-type octahedral molecular sieve (OMS-2) catalyst exhibits strong absorption in the entire solar spectrum region. The Ce ion substituted OMS-2 catalyst can efficiently transform the absorbed solar energy to thermal energy, resulting in a considerable increase of temperature. By combining the efficient photothermal conversion and thermocatalytic ...

a pvc-based membrane containing cerium phosphate was developed. unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. the response of molybdate selective electrode based on this membrane was perfectly linear in the concentratio...

nitrate is an anion of major importance particularly in biological areas. excessive amounts in water supplies indicate pollution from sewage or agricultural effluents. the effects of excessive quantities of nitrate in water are well known. in this research structural modification of natural clinoptilolite by isomorphic substitution was performed. isomorphously substituted zeolite was prepared u...

background: in this study we have prepared the iga solution from normal human plasma using plasma fractionation and ion exchange chromatography. materials and methods: using fractionation of plasma with cold ethanol (starting with 8% ethanol), fraction iii was prepared as a suitable source for iga preparation. then it was treated with caprylic acid for separation of impurities. for enrichment o...

To clarify the Ni species of NiO/SiO2-Al2O3 catalysts that are active for ethylene oligomerization, 18 types were prepared using three Ni-loading methods (i.e., ion-exchange, impregnation, and homogeneous precipitation), with different Ni-loadings (1–20 wt%), examined respect to their structure catalytic activity oligomerization. Characterized by N2 adsorption, powder XRD, FE-SEM, H2-TPR, NH3-T...

Hoveyda-Grubbs type catalysts with cationic tags on NHC ligands were linker-free immobilized on the surface of lamellar zeolitic supports (MCM-22, MCM-56, MCM-36) and on mesoporous molecular sieves SBA-15. The activity of prepared hybrid catalysts was tested in olefin metathesis reactions: the activity in ring-closing metathesis of citronellene and N,N-diallyltrifluoroacetamide decreased in the...

Hydrolysis of ethyl acetate and starch in water and of cellulose in an ionic liquid by using HY and HZSM-5 solid acid catalysts are compared. In water, HZSM-5 is more active than HY. This trend is reversed in ionic liquid. Reactivity differences are explained based on interactions between solvent and catalyst acid site local environments, which depend on zeolite channel structure and Si/Al rati...

Atom transfer radical addition (ATRA) and polymerisation (ATRP) reactions are commonly catalyzed by copper(I) complexes which react, reversibly, with a dormant alkyl halide initiator (RX) releasing a reactive organic radical R˙. The copper catalyst bears a multidentate N-donor ligand (L) and the active catalyst is simply Cu(I)L. The role of the catalyst in these reactions is to abstract a halog...

This study aimed to investigate the kinetics of anion exchange step ferrous ions with Na-X zeolite in a temperature range 20 and 80°C for period up 8 hours. A sulfate heptahydrate solution was used as ion source sodium zeolite. The results showed change physical appearance progress process. catalyst color observed time changed from yellow brown. exchanged contents increased reached 0.519 at aft...

the main objective of this study was to investigate biocompatibility and provide in vivo pharmacological and toxicological evidence for further investigation of the possibility of ph sensitive ion exchange resin microsphere for clinical utilizations. acute toxicity study and general pharmacological studies were conducted on the ph sensitive ion exchange resin microsphere we prepared. the genera...