We describe a fractional-step numerical procedure for the simulation of immiscible three-phase flow in heterogeneous porous media that takes into account capillary pressure and apply it to indicate the existence of a so-called “transitional" wave in at least some multi-dimensional flows, thereby extending theoretical results for one-dimensional flows. The step procedure combines a second-order,...

A spherical liquid-liquid interface can be obtained by dispersing one liquid phase into another to form droplets, which will facilitate the two-phase reactions between the immiscible participating fluids. The phase transfer catalysts assembled at the droplet "wall" catalyze the reactions between the aqueous and organic phases. The study illustrates an interfacial synthetic approach which is ide...

I review the methodology of "high-performance" liquid chromatography as applied to therapeutic drug monitoring. Aside from direct injection of sample, sample cleanup involves miscible and immiscible organic solvent extractions, solid-phase extraction, and size separations. Column considerations are bonded phases, column dimensions, particle size, guard columns, stability, pH range, and reproduc...

An easy assembling-disassembling co-axial capillaries microfluidic device was built up for the production of double droplets. Uniform polymer core-polymer shell particles were synthesized by polymerizing the two immiscible monomer phases composing the double droplet. Thus poly(acrylamide) core-poly(tri(propylene glycol) diacrylate) shell particles with controlled core diameter and shell thickne...

In 1971, Starks introduced the term “phase-transfer catalysis” to explain the critical role of tetraalkylammonium or phosphonium salts (QþX ) in the reactions between two substances located in different immiscible phases [1]. For instance, the displacement reaction of 1-chlorooctane with aqueous sodium cyanide is accelerated many thousand-fold by the addition of hexadecyltributylphosphonium bro...

We show that the widely used model governing the motion of two incompressible immiscible fluids in a possibly heterogeneous porous medium has a formal gradient flow structure. More precisely, the fluid composition is governed by the gradient flow of some non-smooth energy. Starting from this energy together with a dissipation potential, we recover the celebrated DarcyMuskat law and the capillar...

We report on a droplet-producing microfluidic system with electrical impedance-based detection. The microfluidic devices are made of polydimethylsiloxane (PDMS) and glass with thin film electrodes connected to an impedance-monitoring circuit. Immiscible fluids containing the hydrophobic and hydrophilic phases are injected with syringe pumps and spontaneously break into water-in-oil droplet trai...

simultaneous capillary dominated displacement of the wetting and non-wetting phases are processes of interest in many disciplines including modeling of the penetration of polluting liquids in hydrology or the secondary migration in petroleum reservoir engineering. percolation models and in particular invasion percolation is well suited to characterize the slow immiscible displacement of two flu...

The present paper discusses the theoretical studies involved in the development of the differential equations which describe the spontaneous imbibition of water by an oil-saturated rock. The basic assumption underlying in the present investigation is that the oil and water form two immiscible liquid phases and the latter represents preferentially wetting phase. The Saturation of injected water ...

The proof-of-principle for the separation of metals by solvent extraction using two mutually immiscible ionic liquids is given. Cobalt was extracted from the ionic liquid 1-ethyl-3-methylimidazolium chloride to the ionic liquid trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate. A distribution ratio of 44 was obtained. Cobalt could be selectively separated from nickel, with a...