Convergent lines of molecular, carbon-isotopic, and phylogenetic evidence have previously indicated (Hinrichs, K.U., Hayes, J.M., Sylva, S.P., Brewer, P.G., DeLong, E.F., 1999. Methane-consuming archaebacteria in marine sediments. Nature 398, 802±805.) that archaea are involved in the anaerobic oxidation of methane in sediments from the Eel River Basin, o€shore northern California. Now, further...

Catalytic hydroboration of alkynes and alkenes was well demonstrated in the presence neosilyllithium as catalyst pinacolborane, under ambient conditions, to form corresponding alkyl boronic ester products excellent yield. Electron-withdrawing, electron-donating substituents, were tolerated on phenyl rings styrenes. Further, aliphatic substituents yielded desired boronate good quantities. The me...

[reaction: see text] In the presence of NaY faujasite as the catalyst, the reaction of bifunctional anilines (1-4: XC6H4NH2; X = OH, CO2H, CH2OH, and CONH2) with methyl alkyl carbonates [MeOCO2R': R' = Me or MeO(CH2)2O(CH2)2] proceeds with a very high mono-N-methyl selectivity (XC6H4NHMe up to 99%), and chemoselectivity as well, with other nucleophilic functions (OH, CO2H, CH2OH, CONH2) fully p...

The treatment of cyclopropanes having donor and acceptor substituents at the vicinal positions on the cyclopropane ring with a Lewis acid readily generates a 1,3-zwitterion, which reacted with allylsilanes to produce cycloadducts and allylic products. It was found that the yield of the cycloadduct depends on the steric demand of the alkyl substituents on the silicon atom.

The dispersal, quiescent crystallization kinetics and morphology of a series of unique polyethylene ‒polyhedral oligomeric silsesquioxanes (PE-POSS) nanocomposite blends is presented. POSS molecules with long linear alkyl-chain substituents were blended at one composition into a commercial low density polyethylene. Time-resolved Smalland WideAngle X-Ray scattering (SAXS/WAXS) and thermal techni...