A selective ring-closing metathesis (RCM) reaction for the formation of large macrocycles by using latent sulfur chelated ruthenium iodide benzylidenes, readily activated thermal and photochemical (UV-A visible light) stimuli, is reported. For dienes having one terminal alkene internal double bond, specific affinity diiodo alkylidenes unhindered terminus, combined with their reluctance to react...

Silicoaluminophosphate (SAPO-34) molecular sieve doped with transition metals, Mn and Ni, with different molar ratios (Mn/Ni=0.33, 3) were investigated for their activity, selectivity and lifetime in biomethanol to olefins reaction. MnNiAPSO-34 nanostructured catalyst was synthesized by hydrothermal method and addition of metals was carried out by isomorphous substitution into the crystalline f...

• GHG footprints of plastic waste chemical recycling to olefins are quantified. benefits quantified relative incumbent incineration with energy recovery. Chemical provides in the order 0.82 kg CO 2 -eq./kg waste. Future developments further increases from 2030. Dealing heterogeneous – i.e., high polymer heterogeneity, additives, and contaminants lowering greenhouse gas (GHG) emissions productio...

eethylene polymerization catalysts became available in an enormous variety. the challenge in this research is to find catalysts that are able to connect ethylene molecules in such a way that not only linear chains are produced but variations like branched materials that possess very interesting mechanical properties like linear low density polyethylene (lldpe). in this contribution, three diffe...

An efficient, unique, and convenient method for the iodoamidation of olefins with chloramine salts and I(2) in aqueous media is described. This method was applicable to a wide range of olefins, including aromatic, aliphatic, and electron-deficient olefins.

A systematically varied series of conformationally restricted ketones, readily prepared from N-acetyl-D-glucosamine, were tested against representative olefins as asymmetric epoxidation catalysts showing useful selectivities against terminal olefins and, in particular, typically difficult 2,2-disubstituted terminal olefins.