In the present paper, electrochemical methods were used to investigate the behavior of ascorbic acid at a carbon paste electrode modified with 2,2'-((1E)-(1,2 phenylenebis(azanylylidene)) bis(methanylylidene))bis(benzene-1,4-diol) (PBD) and oxidized multiwall carbon nanotubes. The modified carbon paste electrode showed high electrocatalytic activity toward ascorbic acid; the current was enhance...

The present work describes the construction of a new modified graphite-multiwall carbon nanotube paste electrode by casting the appropriate mixture of tetraheptylammonium iodide-iodine as a new modifier. The modified paste electrode was used for the determination of ascorbic acid (AA) in a phosphate buffer solution (pH 2.0). When compared to activated carbon, a graphite and multiwall carbon nan...

A recently constructed polyglycine modified carbon paste electrode (PGMCPE) was employed to evaluate the electrochemical behavior of methyl orange (MO). The developed electrode was characterized by FESEM to understand the morphology of the modified electrode and bare carbon paste electrode (BCPE). The modified electrode exhibits an excellent electrochemical activity towards the oxidation of MO....

Electroanalytical parameters of different graphitic carbon-based electrode materials were compared to select the best one for the pantoprazole electroanalysis. Such parameters include sensitivity, repeatability, residual background current, and signal-tobackground current ratio of the analytical response and such electrodes include conventional carbon-based electrodes such as glassy carbon (GC)...

In the present paper, electrochemical methods were used to investigate the behavior of ascorbic acid at a carbon paste electrode modified with 2,2'-((1E)-(1,2 phenylenebis(azanylylidene)) bis(methanylylidene))bis(benzene-1,4-diol) (PBD) and oxidized multiwall carbon nanotubes. The modified carbon paste electrode showed high electrocatalytic activity toward ascorbic acid; the current was enhance...

Titania nano particles were synthesized at carbon paste electrode by cyclic voltammetry and then it was employed for the determination of acetaminophen in phosphate buffer at pH 7.4. Carbon paste electrode with titania nano particle displayed excellent electrochemically catalytic activities by shifting the oxidation potential of acetaminophen towards the negative side. The mass transfer process...

We report on the electrochemical alteration of a nickel(II) bis-glyoximato complex into nickel-based nanoparticles at a glassy carbon electrode under acid reducing conditions. These particles show electrocatalytic activity towards hydrogen production at +410 mV compared to the bare glassy carbon electrode. Mechanistic insights are discussed based on DFT calculations.

In this research, a glassy carbon electrode was coated with a thin layer of multi-walled carbon nanotubes in the presence of the surfactant and subsequently was electro-polymerized with Poly-L-arginine (P-L-Arg). The prepared electrode was used as an effective sensor for the quantitative detection of Rutin (Ru). The fabricated electrode exhibited good electrochemical performance with low electr...

a thin film of epinephrine (ep) was electrochemically deposited on the surface of glassy carbon electrode previously activated in nahco3 solution. the cyclic voltammograms of the modified electrode indicate that the surface confined ep are strongly dependent on the solution ph, as expected for quinone/hydroquinone functionalities. the ep-modified glassy carbon electrode exhibited catalytic acti...

the electrochemical behavior of a modified carbon paste electrode (mcpe) with n,n′ethylenbis(salicylideneiminato)copper(ii) complex ([cu(ii)-salen]) was investigated as a newsensor for cystein. the britton-robinson buffer with ph 5, 10% modifier in electrode, potentialscanning rate of 20 mvs-1 and puls height of 50 mv were used as the optimum condition for thedetermination of cysteine using car...