This study aimed to examine the effect of CO2 atmosphere during pyrolysis of solid fuel on the gasification of its char by using thermobalance. As the sample, alkali-rich lignin was prepared. The lignin sample was pyrolyzed at heating rate of 1K/s to 700C under CO2 and Ar, and these chars (ligninchar-CO2, ligninchar-Ar) are gasified in air at various temperatures, from 700C to 1140C. The differ...

The effect of fuel composition on gasification process performance was investigated by performing mass and energy balances on a pre-pilot scale bubbling fluidized bed reactor fed with mixtures of plastic waste, wood, and coal. The fuels containing plastic waste produced less H2, CO, and CO2 and more light hydrocarbons than the fuels including biomass. The lower heating value (LHV) progressively...

The potential of supercritical water gasification (SCWG) of macroalgae for hydrogen and methane production has been investigated in view of the growing interest in a future macroalgae biorefinery concept. The compositions of syngas from the catalytic SCWG of Laminaria hyperborea under varying parameters including catalyst loading, feed concentration, hold time and temperature have been investig...

The Wabash River Coal Gasification Repowering Project (WRCGRP), a joint venture between Dynegy Power Corp., and PSI Energy, Inc., began commercial operation in November of 1995. The Project, selected by the United States Department of Energy (DOE) under the Clean Coal Program (Round IV) represents the largest operating coal-gasification combined-cycle plant in the world. This demonstration proj...

Coal gasification is a promising option for the future use of coal. Similarly to gasification in industrial reactors, underground coal gasification (UCG) produces syngas, which can be used for power generation or for the production of liquid hydrocarbon fuels and other valuable chemical products. As compared with conventional mining and surface gasification, UCG promises lower capital/operating...

most of the targeted heavy metals (hms) in sewage sludge ended up in solid residues after pyrolysis and gasification, such as Cu, Zn, Cr, Ni and Pb, which their residual rates were over 70%. The bioavailability of the hms in residues decreased despite their concentrations being higher compared with in sludge. The potential eco-toxicity of each HM were ceased after pyrolysis and gasification of ...

Biochar applications to soils can improve soil fertility by increasing the soil's cation exchange capacity (CEC) and nutrient retention. Because biochar amendment may occur with the applications of organic fertilizers, we tested to which extent composting with farmyard manure increases CEC and nutrient content of charcoal and gasification coke. Both types of biochar absorbed leachate generated ...

The disposal of plastic solid waste (PSW) has become a major worldwide environmental problem. New sustainable processes have emerged, i.e. either advanced mechanical recycling of PSW as virgin or second grade plastic feedstock, or thermal treatments to recycle the waste as virgin monomer, as synthetic fuel gas, or as heat source (incineration with energy recovery). These processes avoid land fi...

This work presents the hydrogen production from steam gasification of palm kernel shell (PKS) at 700 C in the presence of 5% Ni/BEA and 5% Fe/BEA as catalysts. The steam gasification was performed in two-staged reactors to evaluate the effect of calcinations temperature and the steam to biomass ratio on the product gas composition. The catalytic activity of Ni/BEA catalyst decreases with increa...

Solar dried sewage sludge (SS) conversion by pyrolysis and gasification processes has been performed, separately, using two laboratory-scale reactors, a fixed-bed pyrolyzer and a downdraft gasifier, to produce mainly hydrogen-rich syngas. Prior to SS conversion, solar drying has been conducted in order to reduce moisture content (up to 10%). SS characterization reveals that these biosolids coul...