نتایج جستجو برای: free energy activation

تعداد نتایج: 1525654  

Ameneh Alizadeh Ardeshir Shokrollahi, Mehrourang Ghaedi Mojdeh Ranjbar

The objective of this study was to assess the adsorption potential of activated carbon (AC) asan adsorbent for the removal of Murexide (Mu) from aqueous solutions. The influence of variablesparameters including pH, amount of adsorbent, sieve size of adsorbent, temperature and contact timeon Mu removal was studied. Following optimization of variables, the relation between concentrations ofdye re...

Ali Morsali S. Ali Beyramabadi,

Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...

Ashwathaiah Ashwini Devarahosahally Veeranna Kirana Thimmasandra Narayan Ramesh

Calcium ions have very strong affinity and binds effectively to alizarin red dye during staining of biomaterials. This promotes us to choose calcium hydroxide as a low cost adsorbent for the removal of alizarin red dye. Various parameters such as pH, concentration, dose of adsorbent, time, and temperature have been investigated. In addition, enthalpy, entropy, free energy and activation energy ...

Journal: :physical chemistry and electrochemistry 0

the application of conductive coatings on ferritic stainless steel can decrease electrical conductivity. theaim of this research was to investigate the electrical conductivity of cobalt coated aisi 430 ferritic stainlesssteel by pack cementation technique. coated coupons were analyzed using scanning electron microscopy(sem). electrical conductivity of the coated substrates was measured as a fun...

Journal: :journal of agricultural science and technology 2011
y. tulek

the objective of this study was to investigate the drying kinetics of oyster mushroom, pleurotus ostreatus mushrooms were dried using a cabinet-type convective dryer. air temperatures of 50, 60 and 70 oc were used for the drying experiments. the experimental drying data were fitted to different theoretical models to predict the drying kinetics. nonlinear regression analysis was performed to rel...

Fatemeh Naseri Maryam Darvishpoor Saeed Jameh-Bozorghi, Zahra Javanshir

Structural properties, energies behavior and NBO analysis was performed for1-5 prototrophic shift endinelboran where substitutions like H, CH3 and CF3 that were placed on Benzene were investigated by usingDFT-B3LYP/6-311+G** level of theory. The Results show that, -BH2 shift doesn’t take place and a kind of[1,3] shift for borotrophic occured. In prototrophic shift, however, [1,5] transition eas...

Journal: :international journal of nano dimension 0
m. riazian department of engineering, tonekabon branch, islamic azad university, tonekabon, iran

we report on the synthesis, morphology, chemically and structurally of tio2-nio-sio2 nanostructure. the tio2-nio-sio2 nanostructure was synthesized by a method based on the sol-gel method, by the simultaneous gelation of all cations. the coatings were deposited on dried soda-lime glass slides by spin coating. composite powders and coating on glass have been characterized by xrd, sem, edax, and ...

Journal: :journal of particle science & technology 2015
seyed mahhdi latifi mohamad amin ghotbi ravandi

in this work the kinetic data demanded for kinetic modeling were obtained in temperatures 350, 400, 450 and 500 oc by conducting experimentations on a fe-cr nanocatalyst prepared from a novel method and a commercial fe-cr-cu one. the collected data were subjected to kinetic modeling by using two models derived from redox and associative mechanisms as well as an empirical one. the coefficients o...

ژورنال: مواد پرانرژی 2018

In this research, the thermal stability and decomposition kinetics of pentaerythritol tetranitrate (PETN) and Pentastite explosives have been studied experimentally using non-isothermal differential thermal analysis (DTA) and thermo-gravimetric (TG) methods at heating rates of 4.0, 6.0, 8.0 and 10.0 °C/min. The kinetic parameter of activation energy (Ea) and critical ignition temperature fo...

Journal: :iranian journal of mathematical chemistry 2014
a. sanami

let h be a finite dimensional complex hilbert space, b(h)+ be the set of all positive semi-definite operators on h and phi is a (not necessarily linear) unital map of b(h) + preserving the entropy-gibbs transformation. then there exists either a unitary or an anti-unitary operator u on h such that phi(a) = uau* for any b(h) +. thermodynamics, a branch of physics that is concerned with the study...

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