A novel type of deprotonative arylation of nucleophiles was conducted using Et(3)SiH/cat. t-Bu-P4 and the powerful S(N)Ar reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles.

The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, chain compound (H2pipz)FeF5·H2O always occurs as major phase, with compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated from some impurities. latter two compounds feature two-dimensional sheets corner-and edge-shared FeIIIF6 octahedra, resulting in distinct layer architectures. (H2...

A rapid allylic fluorination method utilizing trichloroacetimidates in conjunction with an iridium catalyst has been developed. The reaction is conducted at room temperature under ambient air and relies on Et(3)N·3HF reagent to provide branched allylic fluorides with complete regioselectivity. This high-yielding reaction can be conducted on a multigram scale and shows considerable functional gr...

statement of the problem generally, the main source of fluoride intake is drinking water. excessive consumption of bottled water as a substitute or in addition to the tap water supply may have implications for safe fluoride supplementation. in this study, fluoride contents in six commercial brands of bottled water were measured materials and methods six different brands of bottled drinking wate...

objectives: this study aimed to assess the self-reported knowledge and attitude of dentists towards fluoride prescription. materials and methods: a questionnaire survey was conducted at the national annual dental congress in 2010 in tehran-iran. dentists’ level of knowledge about the preventive effects of systemic and topical administration of fluoride was assessed as well as their attitudes to...

Trapped as molecular solids, the transition metal fluorides ZnF(2) and MeZnF-the latter isolated for the first time-exist as adducts in [(Cp*TiF(3))(8)(ZnF(2))(3)] (1) and [(Cp*TiF(3))(4)(MeZnF)(2)] (2), respectively. Compounds 1 and 2 were obtained in reactions of [Cp*TiF(3)] (Cp*=C(5)Me(5)) with ZnMe(2) and Me(3)SnF in various molar ratios. The single-crystal structure of 1 is shown here; the...

The electrochemical generation of vinyl carbocations from alkenyl boronic esters and boronates is reported. Using easy-to-handle nucleophilic fluoride reagents, these intermediates are trapped to form fully substituted fluorides. Mechanistic studies support the formation dicoordinated through sequential single-electron oxidation events. Notably, this fluorination features fast reaction times Le...

calcium fluoride deposit during fluoride application. uptake and retention of fluoride by saliva depends generally on the concentration of calcium. in this study, the effect of calcium pre-rinse on salivary fluoride concentration after a 900 ppm fluoride mouthwash was investigated.this cross-over double-blind randomized clinical trial was conducted in a girls' dormitory in zahedan university of...