In order to discuss the atomization process of an analyte element occurring in a graphite furnace for atomic absorption spectrometry, we measured variations in the characteristic temperature with the progress of an atomization stage, by using a two-line method under the assumption of a Boltzmann distribution. For this purpose, iron was chosen as the analyte element. Also, the atomic absorption ...

We describe procedures for direct determination of lead and cadmium in blood and urine by flameless atomic absorption spectrophotometry. Before analysis, the samples are pre-ashed in microboats in an ordinary laboratory oven. In this way, many samples can be prepared and pre-ashed simultaneously. We find the procedures presented in this work to be rapid, accurate, and precise.

Flashing or thermodynamic breakup of a liquid jet occurs when a pressurized subcooled or saturated liquid is released to a lower pressure, resulting in violent vapor nucleation, expansion, and break up of the liquid phase. Flashing is known to produce very fine droplet atomization, often not possible by traditional mechanical means. In this work, flashing atomization is introduced in a spray bu...

Direct measurement of lead and cadmium in blood and urine by electrothermal atomic absorption spectrometry with deuterium background correction (D2-AAS) is prone to severe matrix and spectral interferences. We overcame these effects by coating the L'vov platform with ammonium molybdate, reducing the atomization time, introducing a post-atomization cooling step, carefully selecting ashing and at...

Constraints in Alloy, a declarative modeling language, can be translated into Boolean logic and solved with a SAT solver. Atomization is a technique for improving the performance of Alloy analyses; it exploits typing relationships in an Alloy model and produces a semantically equivalent model that can be translated into Boolean form using fewer variables, hence creating a formula that can be so...

A temporal stability analysis was carried out to model the atomization of a swirling viscous annular liquid sheet emanating from an air-blast atomizer subject to inner and outer inviscid swirling air streams. The dimensionless dispersion equation that governs the instability of a viscous annular liquid sheet under swirling air streams was obtained. Numerical solutions to the dispersion equation...

In order to compare and evaluate the atomization process occurring in several types of graphite furnaces for atomic absorption spectrometry, the authors estimated temporal variations in the gas temperature by using a two-line method under the assumption of a Bolzmann distribution. The atomization furnaces employed were a graphite tube, a graphite tube coated with pyrolitic carbon, a graphite tu...

A preliminary study of atomization mechanisms in gas-centered swirl-coaxial injectors for use in rocket engines has been undertaken. Gas-centered swirl-coaxial injectors differ from other injectors in that atomization occurs from a wall-bounded liquid. Few studies of atomization mechanisms in wall-bounded flows exist; some probable atomization processes have been determined, however. These mech...

Newtonian impinging jets have been investigated for decades. However, limited is known about non-Newtonian impinging jets. The present work attempts to improve this situation by performing high-fidelity numerical simulations of non-Newtonian impinging jet dynamics. Emphasis is placed on the near field of the liquid sheet formed by the impingement of two shear-thinning (viscosity deceases with i...

Selected cultures of mercury-resistant bacteria degrade the fungicide-slimicide phenylmercuric acetate. By means of a closed system incorporating a flameless atomic absorption spectrophotometer and a vapor phase chromatograph, it was demonstrated that elemental mercury vapor and benzene were products of phenylmercuric acetate degradation.