نتایج جستجو برای: fischer tropsch
تعداد نتایج: 8187 فیلتر نتایج به سال:
We present in situ experiments to study the possible formation of cobalt carbides during Fischer–Tropsch synthesis (FTS) a Co/TiO2 catalyst at relevant conditions pressure and temperature. Th...
Fischer−Tropsch synthesis (FTS, CO + H 2 → long-chain hydrocarbons) for its great significance in the industry has attracted huge attention since discovery. For Fe-based catalysts, after decades of...
Microkinetics simulations are presented on the intrinsic activity and selectivity of the Fischer-Tropsch reaction with respect to the formation of long chain oxygenated hydrocarbons. Two different chain growth mechanisms are compared: the carbide chain growth mechanism and the CO insertion chain growth mechanism. The microkinetics simulations are based on quantum-chemical data on reaction rate ...
3.1 PRODUCTION OF CLEAN SYNTHESIS GAS......................................................................... 9 3.1.1 Biomass Gasification .............................................................................................. 9 3.1.2 Gas Cleanup.......................................................................................................... 10 3.2 CONVERSION OF SYNTHESIS GAS T...
The structure-activity relations in the alumina-supported cobalt catalysts are studied at the realistic conditions of Fischer-Tropsch synthesis using in situ time-resolved XRD and catalytic measurements. Cobalt sintering during the first 3-5 h of the reaction and cobalt carbidisation at a longer time on stream (>8 h) coincide with catalyst deactivation.
Microkinetics simulations are presented based on DFT-determined elementary reaction steps of the Fischer-Tropsch (FT) reaction. The formation of long-chain hydrocarbons occurs on stepped Ru surfaces with CH as the inserting monomer, whereas planar Ru only produces methane because of slow CO activation. By varying the metal-carbon and metal-oxygen interaction energy, three reactivity regimes are...
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