The spin crossover compound [FeIIH2L2-Me][PF6]2 presents a two-step phase transition. In the intermediate phase, a spin state concentration wave (SSCW) appears resulting from a symmetry breaking (cell doubling) associated with a long-range order of alternating high and low spin molecular states. By combining time-resolved optical and X-ray diffraction measurements on a single crystal, we study ...

Cédric Giraudet, Henri Bataller, Yifei Sun, Aleksandar Donev, José Maŕıa Ortiz de Zárate and Fabrizio Croccolo Laboratoire des Fluides Complexes et leurs Réservoirs, Université de Pau et des Pays de l’Adour, 64600 Anglet, France Courant Institute of Mathematical Sciences, New York University, New York, NY 10012, USA and Departamento de F́ısica Aplicada I, Universidad Complutense, 28040 Madrid, S...

The paper addresses the problem of the existence and quantification of the exergy of non-equilibrium systems. Assuming that both energy and exergy are a priori concepts, the Gibbs “available energy” A is calculated for arbitrary temperature or concentration distributions across the body, with an accuracy that depends only on the information one has of the initial distribution. It is shown that ...

the potential of citrobacter freundii, a gram negative bacteria for the remediation of hexavalentchromium (cr(vi)) and trivalent chromium (cr(iii)) from aqueous solutions was investigated. bioremediationof cr(vi) involved both biosorption and bioreduction processes, as compared to only biosorption processobserved with respect to cr(iii) bioremediation. in the case of cr(vi) bioremediation studi...

Simple bioaccumulation models predict a monotonic increase in concentration with time until an equilibrium concentration is reached. However, unconsidered dynamics including deterministic oscillations occur if realistic time lags are incorporated. Stability criteria are provided for difference and differential forms of the simplest model. These criteria provide the means of identifying systems ...

the removal ofxylenol orange from aqueous solution onto the coal ash was investigated at room temperature. the results show that the adsorption capacity of xylenol orange increased as the adsorption time increased and then equilibrium established after 30 min adsorption time. the results obtained revealed that the coal ash removed about 80 % of xylenol orange from the aqueous solution within 40...