The important biological roles of nitric oxide (NO) have prompted the development of analytical techniques capable of sensitive and selective detection of NO. Electrochemical sensing, more than any other NO detection method, embodies the parameters necessary for quantifying NO in challenging physiological environments such as blood and the brain. In this tutorial review, we provide a broad over...

The Electrochemical Society Interface • Summer 2009 Electrochemical applications to biomedical problems began in the early days of quantitative polarography and this topic was reviewed in a classic book by Březina and Zuman published over 50 years ago.1 In recent years, commercial electrochemical enzyme sensors have become the method of choice for diabetic patients to measure glucose in their b...

A bifunctional probe (FecNC), containing a recognition part and an electrochemical active center, was applied to electrochemical detection of GG mismatch duplexes. The preparation of gold electrodes modified by mismatch and complementatry duplexes was characterized by electrochemical impedance spectroscopy (EIS) and optimized for better detection in terms of self-assembly time, hybridization ti...

In this study, the electrochemical mechanism of catechol in presence and absence of nitrite ion, is investigated in phosphate buffer medium (pH=7) using platinum electrode through cyclic voltammetry method in various scan rates. Electrochemical oxidation of catechol showed how quinone has changed to o-benzoquinone and also how o-benzoquinone has reacted with nitrite ion and potential scan rate ...

The preparations and characterization of polypyrrole – polyethylene glycol (PPy-PEG) films are reported in this paper. The composite films were synthesized by electrochemical method in 0.2 mol·L-1 Py and 5% PEG in 0.2 mol·L-1 oxalic acid. The electrochemical behaviour of PPy and PPy-PEG coatings has been investigated in phosphate buffer solution (PBS) by cyclic voltammetry, Tafel plots and elec...

Magnetoelastic alloy films have been used as a working electrode in an electrochemical cell. This material allows magnetic interrogation of electrochemical deposition. This technique was used to monitor the electrochemical deposition of polypyrrole by multisweep (CV) and potentiostatic methods. Since the determination of the mass-sensitive magnetoelastic film's resonance frequency is based on m...

growing the water consuming and shortage of available fresh water resources, make “effluent reuse” an unavoidable issue in industry for supplying a part of needs for required water. on the other hand, increment in the production of paper products from wood and recycling their consumed products which release pollutants to the environment has increased the environmental concerns. thus, in present...

In this study, boroxine derivative (K₂[B₃O₃F₄OH]) was tested as an inhibitor of horseradish peroxidase (HRP) by spectrophotometric and electrochemical methods. The activity of horseradish peroxidase was first studied under steady-state kinetic conditions by a spectrophotometric method which required the use of guaiacol as a second substrate to measure guaiacol peroxidation. The results of this ...