Using a graphite crucible as the counter-electrode, platinum microprobes with an aspect ratio of 30 and a tip apex radius less than 100 nm were fabricated by an electrochemical discharge etching process. The "neck-in" structure on the platinum wire induced by the electrical discharge at the liquid-air interface plays a key role in the probe shape and the voltage of the following pure electroche...

A new sensitive electrochemical sensor for the detection of copper ions based on the copper ion assisted etching of Au@Ag nanoparticles was developed in this work. Since copper ions could greatly catalyze the etching process of the silver shell of Au@Ag nanoparticles in the presence of thiosulfate solutions, leading to an obvious decrease of the linear sweep voltammetry (LSV) signals of silver,...

The PAN-based carbon fibers were modified using anodic oxidation method with different electrolyte such as sulfuric acid, sodium sulfate and sodium hydroxide for improving its surface properties and its composites interphase properties. It is well know that different electrolyte have different oxidizability and electrochemical characterization. The influence of different electrolytes on the eff...

Multilayer nanowires tailored with alternating AuFe porous layers and Au nonporous segments were fabricated by galvanic square-wave pulsed electrodeposition from a AuFe cyanide-free electrolyte. Control of porosity and composition was achieved via modulation in pulsed time and applied current density. Nanowires with decreased porosity were observed upon increasing time of the AuFe alloy layer o...

Can isotropic wet chemical etching be controlled with a spatial resolution at the nanometer scale, especially, for the repetitive microfabrication of hierarchical 3D m-nanostructures on the continuously curved surface of functional materials? We present an innovative wet chemical etching method called “electrochemical buckling microfabrication”: first, a constant contact force is applied to gen...

This article reports on the studies of porous GaN prepared by ultra-violet (UV) assisted electrochemical etching in a solution of 4:1:1 HF: CH3OH:H2O2 under illumination of an UV lamp with 500 W power for 10, 25 and 35 minutes. The optical properties of porous GaN sample were compared to the corresponding as grown GaN. Porosity induced photoluminescence (PL) intensity enhancement was found in t...

The demand for ultrathin microprobes has been growing in diverse fields such as scanning probes in scanning tunneling microscopy ~STM!, atomic force microscopy ~AFM!, and micromachining. Mechanical fabrication methods generally involve precision mechanical operation such as turning, grinding, and wire electrodischarge grinding ~WEDG!. The convenience and variety of shaping in this approach is o...

La0.6Sr0.4CoO3 d thin films of varying thicknesses (20–170 nm) were prepared by pulsed laser deposition on yttria-stabilized zirconia (100) substrates, and their electrochemical electrode performance was correlated with the chemical surface composition and microstructure (e.g. porosity, surface area). The surface cation composition was analyzed by an atomic etching procedure with on-line induct...

The separation of chemical vapor deposited (CVD) graphene from the metallic catalyst it is grown on, followed by a subsequent transfer to a dielectric substrate, is currently the adopted method for device fabrication. Most transfer techniques use a chemical etching method to dissolve the metal catalysts, thus imposing high material cost in large-scale fabrication. Here, we demonstrate a highly ...

In the presented work the dynamic simulation of a silicon anodization process is performed. Two mechanisms of etch form development (diffusion in electrolyte, current flow) are considered and simulated. Influence of electrolyte conductivity and radius of the opening in the masking layer is discussed.