Abstract Sulfinyl radicals – one of the fundamental classes S-centered have eluded synthetic application in organic chemistry for over 60 years, despite their potential to assemble valuable sulfoxide compounds. Here we report successful generation and use sulfinyl a dual radical addition/radical coupling with unsaturated hydrocarbons, where readily-accessed sulfones serve as precursor. The stra...

We report total cross-section measurements for positron scattering on cyclic hydrocarbons: benzene, aniline, and cyclohexane. Measurements were done by an absolute transition method in the energy range 1.5–20 eV (0.4–20 eV for cyclohexane). High cross-sections for all measured molecules were observed at low energies. In the case of cyclohexane the cross-section in the zero energy limit tends to...

Objectives. The increased use of unmanned aerial vehicles necessitates the search for jet fuels based on hydrocarbon materials with high energy intensity and physical density. purpose work was to analyze influence various factors mass hydrocarbons. This analysis is required substantiate algorithm locating energy-intensive CnHm structures. Methods. Combustion calculated using additive procedures...

Both diastereomers of the tris-allene, cyclododeca-1,2,5,6,9,10-hexaene have been obtained using a triple cyclopropylidene-allene rearrangement. On the NMR timescale, one has D3 symmetry, and is the smallest hydrocarbon synthesised to have this symmetry, and the second has C2 symmetry.

The goal of this study was to monitor emission of chemicals at a factory where plastics products were fabricated by a new robotic (impregnated tape winding) production process. Stationary and personal air measurements were taken to determine which chemicals were released and at what concentrations. Principal component analyses (PCA) and linear regression were used to determine the emission sour...

Herein we reveal a straightforward supramolecular design for the H-bonding driven J-aggregation of an amine-substituted cNDI in aliphatic hydrocarbons. Transient absorption spectroscopy reveals sub-ps intramolecular electron transfer in isolated NDI molecules in a THF solution followed by a fast recombination process, while a remarkable extension of the excited state lifetime by more than one o...

Manual solid-phase microextraction (SPME) coupled with gas chromatography-mass spectrometry is investigated as a possible alternative for the determination of petroleum hydrocarbons in soils. Spiked onto an agricultural soil is a commercial diesel fuel (DF) with the following composition by weight: 12% linear alkanes, 52% saturated hydrocarbons (branched and cyclic), 21% alkylated aromatic hydr...

In this study, the interaction pattern and energies of a series of hydrocarbon dimers have been investigated by using a highly reliable quantum chemical method (M06-2X/cc-pVTZ). Saturated and unsaturated hydrocarbons in both cyclic and acyclic forms have been modelled to study their interaction. These dimers are found to involve different types of noncovalent interactions such as π-π (dimer of ...

Herein we reveal a straightforward supramolecular design for the H-bonding driven J-aggregation of an amine-substituted cNDI in aliphatic hydrocarbons. Transient absorption spectroscopy reveals sub-ps intramolecular electron transfer in isolated NDI molecules in a THF solution followed by a fast recombination process, while a remarkable extension of the excited state lifetime by more than one o...