A novel covalently modified glassy carbon electrode with glutamic acid has been fabricated via an electrochemical oxidation procedure and was applied to the catalytic oxidation of uric acid (UA) and ascorbic acid (AA), reducing the overpotentials by about 0.2 V and 0.3 V, respectively. Based on its strong catalytic function toward the oxidation of UA and AA, the modified electrode resolved the ...

this study reports the synthesis of chitosan anchored schiff base, ([2-oxo-1h-indol-3-ylidene] amino) chitosan and its cu (ii) metal complex. the complex was characterized by elemental analysis, ft-ir spectrum, thermogravimetry analysis .the crystallinity of the compound was analyzed by powder x-ray diffraction technique. the catalytic efficiency of complex was studied in the oxidation of alcoh...

cobalt chromite (cocr2o4) with normal spinel structure, shows catalytic activity for oxidation of unburned methane in the natural gas vehilcles (ngv). in this study, cocr2o4 nanoparticles were synthesized through a conventional co-precipitation technique and investigated for the catalytic combustion of methane. cobalt nitrate hexahydrate, chromium nitrate nonahydrate and ammonia solution (25%) ...

In this research, Keggin-type polyoxometalate, H5PMoV2O40 (denoted as PMoV) was immobilized on modified NiFe2O4 nanoparticles to produce a magnetically separable catalyst. This catalyst was characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), cycli...

In this work, two types of solvents ethanol or water were used in preparation of the LaFeO3 catalysts by citrate sol gel method. The obtained samples were subjected to various calcination temperatures in order to study the catalytic activity and stability for methanol electro-oxidation by XRD, cyclic voltammetry and chronoamperometry. The crystallinity of the LaFeO3 ph...

Oxidation of formaldehyde (HCHO) is very important, owing to its use in fuel cells. Modification of electrodes surfaces is an excellent way to decrease the overpotentials as well as to increase the current density of the voltammetric response.pt as most efficient metal catalyst can easily be poisoned by product of oxidation and also it has high cost. In this work an efficient and low cost elect...

The total oxidation of toluene at a wide temperature range (200–500 oC) over micro/mesoporous platinated catalysts has been investigated about activity, selectivity to CO2 and CO, catalyst's stability versus coke deposition and reaction kinetics. Kinetic of toluene oxidation was measured under various oxygen and toluene pressures and als...

a novel chemically modified electrode containing prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. the electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. the film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. results showed at bare gc electrode, a...

Background: Spent caustic contains noxious components such as sulfide species and also high chemical oxygen demand content (COD). Oxidation of these materials to caustic and sulfate species is mostly the rate-controlling step within catalytic oxidation of spent caustic. Methods: In this study, the kinetics of catalytic oxidation of spent caustic and the regeneration methodology of the sulfidic...