On Cu/ZrO2 catalysts, variation of the Cu loading from 0.2 wt% to 80 allows assessing influence Cu-ZrO2 interface on methanol steam reforming (MSR) performance by steering particle size and morphology, revealing contribution potential active sites at intrinsic relative contributions support surface fraction. As ZrO2 influences both CO2-selective selectivity-spoiling MSR reaction channels, disen...

Metal adhesion on metal oxides is strongly controlled by the oxide surface structure and composition, but lack of control over the surface conditions often limits the possibilities to exploit this in opto- and micro-electronics applications and heterogeneous catalysis where nanostructural control is of utmost importance. The Cu/ZnO system is among the most investigated of such systems in model ...

Charge trapping properties of electrons and holes in copper-doped zinc oxide (ZnO:Cu) films have been studied by scanning probe microscopy. We investigated the surface potential dependence on the voltage and duration applied to the copper-doped ZnO films by Kelvin probe force microscopy. It is found that the Fermi Level of the 8 at.% Cu-doped ZnO films shifted by 0.53 eV comparing to undoped Zn...

The Cu/ZnO nanocomposite films have been synthesized by cathodic electrodeposition and characterized using X-ray diffractometer (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), photoluminescence (PL) and field emission microscope (FEM). The XRD pattern shows a set of well defined diffraction peaks, which could be indexed to the wurtzite hexagonal phase of ZnO. ...

NPS SYNTHESIS, CHARACTERIZATION AND AZO-DYE DEGRADATION A facile cost effective wet chemical method of synthesis is proposed for Cu-NPs, CuO-NPs and Cu-doped ZnO-NPs. The nanomaterials are opto-physically characterized for nano standard quality. Cu-doped ZnO-NPs based catalytic system is found to possess most efficient photocatalytic activity in degradation of two organic azo-dyes namely methyl...

New highly mixed phases have been identified in Cu/ZnO systems by EXAFS and XANES at both the Cu and Zn K-edge. The phases were generated by ball-milling Cu(2)O/ZnO mixtures under three different atmospheres of synthetic air (SA), SA + CO(2) and CO(2). The system milled in CO(2) shows disproportionation of Cu(2)O into Cu(0), Cu(1+) (cuprite Cu(2)O-type phase) and Cu(2+) (tenorite CuO-type phase...

Cu/ZnO catalysts were synthesized on Al2O3-ZrO2 support via impregnation method with addition of manganese and niobium promoters. Samples calcined at 181, 350 518 ºC. Different characterization techniques such as H2-TPR CO2-TPD used to study the catalytic reduction behavior basicity, respectively. studies shows that all occurred range temperature between 237 ºC 265 The profiles showed calcinati...

In this study, ZnO nanopowders and ZnO doped with metals (Cu , Ag- doped ZnO) and (Cd, Ag- doped ZnO) were synthesized by the sol-gel method in order to investigation on the codoping effect on the band gap and photocatalytic activity of ZnO. The synthesized samples are characterized by IR spectroscopy technique. Moreover, the absorption coefficients of the ZnO, Ag-Cd-ZnO and Ag-Cu-ZnO were anal...

Scanning tunnelling microscopy (STM) and X-ray photoelectron spectroscopy (XPS, AES) were used to study MOCVD of Cu-clusters on the mixed terminated ZnO(10% 10) surface in comparison to MBE Cu-deposition. Both deposition methods result in the same Cu cluster morphology. After annealing to 670 K the amount of Cu visible above the oxide surface is found to decrease substantially, indicating a sub...