3 | P a g e Abstract This thesis is concerned with the synthesis and characterisation of TiO2 based photocatalyst thin films and the assessment of their antimicrobial properties. When exposed to light of wavelength less than 380 nm TiO2 films can demonstrate self-cleaning and self-disinfecting properties. This is due to photocatalytic processes occurring on the film surface resulting in film su...

A new microelectronic package was designed for a high-power light-emitting diode (LED). The objective was to build a package that enables the LED to operate with currents as high as 2 Amps. An innovative thin-film interface has been developed to electrically connect the cathode of the LED die to a 22AWG Cu wire. This thinfilm interface is wirebondable and solderable, and consists of three layer...

Synthesis of structured macroporous TiO2 thin films on quartz substrate (macroTiO2/Q) was performed by a dip-coating method using poly(methyl methacrylate) (PMMA) microspheres as template. Obtained TiO2 thin films kept high transparency and had anatase crystalline structure. SEM observations revealed that the macropores were uniformly formed on the film surface. The size of macropores was quite...

When titanium dioxide (TiO2) is exposed to nearultraviolet light, it exhibits strong bactericidal activity. Anatase phase of TiO2 film was prepared by anodizing pure titanium coupons (substrate). Atomic force microscopy (AFM) technique was used to image the transformation of titanium surface to TiO2 surface on anodization. We observed wide distribution of TiO2 particles ranging from submicron t...

In this work, tetra(4-carboxyphenyl)porphyrin (TCPP) and two Anderson-type polyoxomolybdates (containing Cu Zn, respectively; CuPOM, ZnPOM) were synthesized deposited on TiO2 thin films. The properties of the obtained materials characterized through UV–vis spectroscopy, Fourier transform infrared spectroscopy (FT-IR), diffuse reflection scanning electron microscopy (SEM) energy-dispersive X-ray...

We developed a new method of fabricating a divalent copper ion (Cu(2+)) modified DNA thin film on a glass substrate and studied its magnetic properties. We evaluated the coercive field (Hc), remanent magnetization (Mr), susceptibility (χ), and thermal variation of magnetization with varying Cu(2+) concentrations [Cu(2+)] resulting in DNA thin films. Although thickness of the two dimensional DNA...

Inkjet printing technique is proposed for the fabrication of titanium dioxide (TiO2) photoanodes with a synthetic colloidal TiO2 ink. The resultant electrodes were characterised usingmaterials characterisation methods (such as scanning electronmicroscope, X-ray diffraction andUV–vis spectrophotometer) aswell as photoelectrochemical means. The preliminary results indicate that the nanostructure ...

We describe the fabrication of a nanometer-size electrode based on an insulating TiO2 film and a metal nanoparticle (NP). The TiO2 film is deposited on the conducting Pt surface of an ultramicroelectrode (UME) to block electron transfer (ET) to solution species. The film thickness is, however, thin enough to enable tunneling to Pt NPs; thus, the subsequent contact of metal NP to the TiO2 film r...

A tubular array of TiO2 nanotubes on Ti matrix was used as a support for Ag or Cu sputter-deposited layers intended for surface-enhanced Raman scattering (SERS) investigations. Composite samples of Ag/TiO2-nanotube/Ti and Cu/TiO2nanotube/Ti were studied with the aid of scanning electron microscopy (SEM) and Auger electron spectroscopy (AES and SAM) to reveal their characteristic morphological a...

In this paper, a thin transparent titania (TiO2) film was coated on the surface of flexible poly(ethylene terephthalate) (PET) film using the sol-gel method. The surface properties of the obtained TiO2/PET film were further improved by RF glow discharge oxygen plasma as a function of exposure time and discharge power. The changes in hydrophilicity of TiO2/PET films were analyzed by contact angl...