نتایج جستجو برای: cu ii

تعداد نتایج: 632297  

Journal: :International journal of pharmaceutics 2008
Mei Yang Guohui Cui Ming Zhao Chao Wang Lili Wang Hu Liu Shiqi Peng

The complexation of Cu(II) with previously synthesized thrombolytic peptides, Pro-Ala-Lys (6), Arg-Pro-Ala-Lys (7), Ala-Arg-Pro-Ala-Lys (8), Gly-Arg-Pro-Ala-Lys (9) and Gln-Arg-Pro-Ala-Lys (10), resulted in the formation of complexes, Cu(II)-(Pro-Ala-Lys) (6-Cu), Cu(II)-(Arg-Pro-Ala-Lys) (7-Cu), Cu(II)-(Ala-Arg-Pro-Ala-Lys) (8-Cu), Cu(II)-(Gly-Arg-Pro-Ala-Lys) (9-Cu) and Cu(II)-(Gln-Arg-Pro-Ala...

2016
Daniel Admasu Desam Nagarjuna Reddy Kebede Nigussie Mekonnen

Two selective and sensitive reagents, 2-acetylpyridine thiosemicarbazone (2-APT) and 3-acetylpyridine thiosemicarbazone (3-APT) were used for the spectrophotometric determination of Cu(II). Both reagents gave yellowish Cu(II) complex at a pH range of 8.0-10.0. Beer's law was obeyed for Cu(II)-2-APT and Cu(II)-3-APT in the concentration range of 0.16-1.3 and 0.44-1.05 µg/mL, respectively. The mo...

Journal: :The Journal of biological chemistry 2011
Jeppe T Pedersen Jesper Østergaard Noemi Rozlosnik Bente Gammelgaard Niels H H Heegaard

Cu(II) ions are implicated in the pathogenesis of Alzheimer disease by influencing the aggregation of the amyloid-β (Aβ) peptide. Elucidating the underlying Cu(II)-induced Aβ aggregation is paramount for understanding the role of Cu(II) in the pathology of Alzheimer disease. The aim of this study was to characterize the qualitative and quantitative influence of Cu(II) on the extracellular aggre...

Journal: :journal of sciences islamic republic of iran 0

co(ii) and cu(ii) promoted base hydrolysis of 2-cyano, 1, lo-phenanthroline was studied. at 298.2°k, cu(ii) reaction is more efficient (by a factor of 20) than either co(ll) and its analogues ni(ii) in promoting base hydrolysis.

Journal: :journal of chemical health risks 0
a. moghimi department of chemistry, varamin (pishva) branch , islamic azad university, varamin, iran h. mosalai department of chemistry, mahshahr branch, islamic azad university, mahshahr, iran h. hashemi moghadam department of chemistry, damghan branch, islamic azad university, damghan, iran

a simple method has been developed for the preconcentration of copper(ii) based on the adsorption of its modified nano polyacrylonitrile fiber. modified nano polyacrylonitrile fiber (panf) was prepared by adding of acrylic fibers to msethanolamine (mma) with different concentration solutions. the stability of a chemically modified nano polyacrylonitrile fiber especially in concentrated hydrochl...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی خواجه نصیرالدین طوسی - دانشکده علوم پایه 1393

در این پایان نامه ، واکنش نمک دو عنصر واسطه مس(ii) و مس(i) و روی (ii) با برخی از لیگاندهای2،2:6،"2-ترپیریدین-4-استخلاف دار بررسی شد. واکنش لیگاند 4-هیدروکسی-2،2:6،"2-ترپیریدین (tpyoh) با zn(ch3coo).2h2o منجر به تشکیل کمپلکس [zn(tpyo)(oocch3)] شد که لیگاند tpyo- به عنوان یک لیگاند چهاردندانه از طریق اتم اکسیژن ، با کوئوردیناسیون هشت وجهی انحراف یافته znn3o3 بـرای تشکـیـل پلیـمر یــک بعــدی عمل م...

پایان نامه :وزارت علوم، تحقیقات و فناوری - پژوهشگاه شیمی و مهندسی شیمی ایران - پژوهشکده شیمی تجزیه و معدنی 1389

رشد و توسعه سنسورهای نوری شیمیایی (اپتود) نسبت به انواع دیگر سنسورها در سال های اخیر بسیار سریع و چشمگیر بوده است. استفاده از اپتودها به علت مزیت هایی نظیر حساسیت خوب، گزینش پذیری بالا، سهولت اجرا و کم هزینه بودن در شیمی تجزیه مورد توجه قرار گرفته است. طراحی اپتود مورد استفاده در این پروژه ، تثبیت شناساگر دی تیزون روی غشای تری استیل سلولز، برای اندازه گیری جداگانه ی cu(ii) و hg(ii) قبلا گزارش ...

2015
Md. Abdul Motin Md. Matiar Rahman M. A. Hafiz Mia K. M. Salim Reza M. A. Aziz Abul Hashem

The voltammetric study of Cu (II) in presence of aspartic acid (Aa) and L-phenyl alanine (Pa) respectively has been carried out in buffer solution of different pH, scan rate and variation of Aa or Pa concentration. Cu(II) in presence of Aa and Pa has been found to undergo two anodic peaks follows two step two electron transfer anodic reaction. The peak positions of the voltammogram of Cu(II) in...

Journal: :Dalton transactions 2013
Kathleen Servaty Emilie Cauët Fabrice Thomas Javiera Lambermont Pascal Gerbaux Julien De Winter Margriet Ovaere Leen Volker Nathalie Vaeck Luc Van Meervelt Wim Dehaen Cécile Moucheron Andrée Kirsch-De Mesmaeker

In view of preparing Cu polynuclear complexes with dipyrromethene ligands, the mononuclear complexes [Cu(II)(dipy)2] (dipyH = 5-phenyldipyrromethene) and [Cu(II)(dpdipy)2] (dpdipyH = 1,5,9-triphenyldipyrromethene) have been prepared and characterized by X-ray crystallography, mass spectrometry and EPR spectroscopy. Their peculiar redox and spectroscopic (absorption/emission) behaviours are disc...

Journal: :Dalton transactions 2010
Shu-Pao Wu Kun-Ju Du Yi-Ming Sung

9,10-Anthraquinone-based chemosensor 1 indicates the presence of Cu(II) ions among other transition metal ions with high selectivity by a color change from yellow to dark red. Chemosensor 2 shows binding toward Cu(II), Ni(II) and Co(II) with color changes from yellow to dark red, red and pale green, respectively. Especially, Co(II) binding with chemosensor 2 causes significantly green fluoresce...

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