Many coal-fired power plants are implementing ammonia-based technologies to reduce NO(x) emissions. Excess ammonia in the flue gas often deposits on the coal fly ash. Ammonia can form complexes with many heavy metals and change the leaching characteristics of these metals. This research tends to develop a fundamental understanding of the ammonia impact on the leaching of some heavy metals, exem...

BACKGROUND South-Western Sardinia (SWS) is a high risk area for Multiple Sclerosis (MS) with high prevalence and spatial clustering; its population is genetically representative of Sardinians and presents a peculiar environment. We evaluated the MS environmental risk of specific heavy metals (HM) and geographical factors such as solar UV exposure and urbanization by undertaking a population-bas...

Abstract The 1,500-km-long Banatitic Magmatic and Metallogenetic Belt (BMMB) of Romania, Serbia and Bulgaria is a complex calc-alkaline magmatic arc of Late Cretaceous age. It hosts a variety of magmatic-hydrothermal Cu, Au, Mo, Zn, Pb and Fe deposits, including Europe’s only world-class porphyry-copper deposits. Regional metallogeny can be linked to subduction of the Vardar Ocean during the La...

Metallic mineral deposits represent natural geochemical anomalies of economically valuable commodities but, at the same time, their weathering may have negative environmental implications. Cu-sulfide been recognized as with a particularly large footprint. However, different Cu result in significantly impacts, mostly depending on conditions, but also geological characteristics (mineralogy, geoch...

Natural cases of dealloying or stress-corrosion cracking in copper alloys normally occur in oxygenated solutions, where the cathodic reactant is O2 or Cu2+. Within cavities or under deposits, the local environment is enriched in cuprous ions (e.g. CuCl2-, Cu (NH3)2+) and the potential is close to the Cu/Cu+ equilibrium. Such conditions can be simulated macroscopically by stirring powdered Cu2O ...

Pyritic shale horizons of the Newland Formation (Belt Series, Mid-Proterozoic) show striking similarities to Proterozoic pyritic shales elsewhere that are host to major lead-zinc deposits, such as Mt. Isa and McArthur River. However, in contrast to these deposits the pyritic shales of the Newland Formation contain only minute quantities of lead and zinc. Elevated concentrations of lead and zinc...