The unusual reactivity of hafnocene complexes in comparison to their titanium and zirconium analogues was dramatically demonstrated in the recent functionalization of coordinated N2 and the coupling of CO2 and N2 to a substituted hydrazine product. The differences in their structure and bonding were also noticed; for example, the s and p ratio of the diene bonding in (s-cis-h-diene) metallocene...

Additive manufacturing (AM) enables fully dense biomimetic implants in the designed geometries from preferred materials such as titanium and its alloys. Titanium aluminum vanadium (Ti6Al4V) is one of pioneer metal alloys for bone implant applications, however, reasons eliminating toxic effects Ti6Al4V maintaining adequate mechanical strength have increased potential commercially pure (cp-Ti) to...

Titanium and its alloys have been used in a broad range of products such as biomedical implants due to their high specific strength, corrosion resistance, biocompatibility. Improvement microstructure mechanical properties commercially pure (CP) titanium is usually performed by cold rolling controlled atmosphere heat treatment. However, this an energy-intensive, expensive, multi-stage process ac...

PURPOSE The aim of this in vitro study was to investigate the adhesion of initial colonizer, Streptococcus sanguis, on resin, titanium and zirconia under the same surface polishing condition. MATERIALS AND METHODS Specimens were prepared from Z-250, cp-Ti and 3Y-TZP and polished with 1 µm diamond paste. After coating with saliva, each specimen was incubated with Streptococcus sanguis. Scannin...

The innovative titanium-magnesium composite (Ti-Mg) was produced by powder metallurgy (P/M) method and is characterized in terms of corrosion behavior. Material and methods: Two groups of experimental material, 1 mass% (Ti-1Mg) and 2 mass% (Ti-2Mg) of magnesium in titanium matrix, were tested and compared to commercially pure titanium (CP Ti). Immersion test and chemical analysis of four soluti...

an experiment was conducted to determine apparent ileal digestibility of crude protein (cp) and amino acids (aa) and digestible cp and aa of fish meal (fm) in 21-d-old broiler chickens using the regression technique. four diets containing 0, 1, 2, and 3% fm in place of cornstarch were formulated with fm as the sole contributor of cp and aas in the sequential diets. eighty 14-d-old broiler chick...

Methyl triflate reacts with the metastable azoxymetallacyclopentene complex Cp*2Zr(N(O)NCPhCPh), generated in situ from nitrous oxide insertion into the Zr-C bond of Cp*2Zr(η2-PhCCPh) at -78 °C, to afford the salt [Cp*2Zr(N(O)N(Me)CPhCPh)][O3SCF3] (1) in 48% isolated yield. A single-crystal X-ray structure of 1 features a planar azoxymetallacycle with methyl alkylation taking place only at the ...

BACKGROUND Many chemical and physical modifications of titanium surfaces were introduced, aiming at improving surface bioactivity, but few comparative evidence exists. OBJECTIVE To evaluate histologically in minipigs the osseointegration of implants made of commercially pure (CP) titanium or titanium alloy, treated by different roughening procedures. MATERIAL AND METHODS Three sandblasted a...

The results of XPS measurements of commercially pure titanium (cp-Ti) before and after chemical treatment are presented. We have measured XPS spectra of core levels (Ti 2p, O 1s, C 1s, F 1s) and valence bands of coarse-grained cp-Ti before and after standard acid treatment accepted in dentistry (in 1% HF and 40% HF for 1 min). It is found, that acid treatment of cp-Ti reduces the content of hyd...