Chemically modified Nafion composite membranes were successfully fabricated using five kinds of protic ionic liquids (PILs) with different cations, 1-butylammonium methanesulfonate (BA-MS), tributylammonium methanesulfonate (TBA-MS), 2,4,6-trimethylphenylammonium methanesulfonate (TMA-MS), butane-1,4-diammonium methanesulfonate (BDA-MS), and N-(2-aminoethyl)ethane-1,2-diammonium methanesulfonat...

in this work, the interfacial interfacial polymerization (ip) technique was employed using terephthaloyl chloride (tpc) and p-phenylenediamine (ppd), as reactant monomers, to prepare poly(paraphenylene terephthalamide) thin film composite (tfc) nanofiltration on polyethersulphone (pes) support layer. the effects of six different anionic and non-ionic surfactants, in the aqueous phase on the mor...

Chitosan (CS) and alginate (Alg) are complementary in their membrane performance, but the combination of them is normally difcult to use due to their different solubilities. Layer-by-Layer deposition appears to be an effective method for improving the separation efciency of a composite membrane. In this work, the polyelectrolyte multilayer composite membranes (PEMCMs) wer...

A PEBAX-nano zeolite X mixed matrix membrane was fabricated and operationally characterized using single gas (CO2) permeation. X-ray diffraction (XRD) analysis was used to study the arrangement of polymer chains of mixed matrix membrane. The membranes were characterized by scanning electron microscopy (SEM) to study cross-sectional morphology. The single gas permeability were carried...

Composite Nanofiltration membranes were fabricated by incorporating Carbon Nanotubes (CNT) and Polyvinylidene Fluoride (PVDF) membranes. A suspension was prepared by dispersing CNT (30 minutes of sonication) in Dimethyl Sulfoxide (DMSO) solvent for 0.5 mg/ml. This suspension after vacuum filtration dispersed over PVDF membrane of pore size 0.22μm. Excess DMSO was removed by washing using Ethano...

In this paper, rod-like chitin whisker was used as a filler to reinforce the chitosan membrane, and a series of composite membranes were prepared by casting-evaporation method. Mechanical testing shows that tensile strength of the resulting composite membrane with 3 wt% chitin whisker content reaches up to 110.3 MPa, which is about 2.8 times than that of neat chitosan membrane (38.5 MPa), and m...

Thin Film Composite – Polyamide (TFC-PA) are commonly used reverse osmosis (RO) membranes in water desalination and waste water applications. Their poor chlorine tolerance and fouling characteristics constrain the life and performance leading to stringent chemical pretreatment requirements. In this context, development of fouling resistant and chlorine tolerant RO membranes would be relevant to...

One of the limiting factors in good performance of forward osmosis (FO) membranes is the internal concentration polarization (ICP). To reduce ICP, thin film nanocomposite forward osmosis (TFN-FO) membranes were fabricated by adding different amounts of graphene oxide (GO) nanoplates (0-1 wt. %) to polymer matrix of polysulfone (PSf) substrate. The prepared nanocomposite membranes exhibited both...

polyacrylonitril (pan)-supported chitosan (cs) nanocomposite membranes were prepared by cross-linking the cs with 3-aminopropyl-triethoxysilane (apteos) via sol-gel method. pervaporative performances of the cs-sio2/pan membrane for dehydration of aqueous alcohol solutions were investigated. from sem cross-sectional images of the membrane, the spongy pores and the finger-like pores were found in...

Pervaporation membrane technology plays an important role in production of renewable bio-fuels. To improve the separation performance of polymeric membranes, an effective approach is development of mixed-matrix membranes containing high-performing fillers such as metal-organic frameworks. Towards practical application, hollow fiber could be an ideal substrate for mixed-matrix composite membrane...