We present a comprehensive micro- and macrorheological study of the effect of weak depletion attraction (Ψdep ≈ 1-10 kBT) on dense colloidal suspensions stabilized by short-range repulsive interactions. We used aqueous polymer dispersions as model system and demonstrated the unique capabilities of multiple particle tracking (MPT) to disclose structural changes in such technically important syst...

A combination of confocal microscopy and rheology experiments, Brownian dynamics (BD) and molecular dynamics (MD) simulations and mode coupling theory (MCT) have been applied in order to investigate the effect of shear rate on the transient dynamics and stress-strain relations in supercooled and glassy systems under shear. Immediately after shear is switched on, the microscopic dynamics display...

Liquid crystal suspensions including variousmicroand nano-colloidal particles have recently been received great attention for many practical applications such as nanosensors and devices, etc. When large colloidal particles of micronscale are dispersed in a uniform nematic liquid crystal phase, the colloidal particles disturb a long-range orientational order of the nematic phase. For a strong an...

The liquid-gas transition of an electroneutral mixture of oppositely charged colloids, studied by Monte Carlo simulations, is found in the low-temperature-low-density region. The critical temperature shows a nonmonotonous behavior as a function of the interaction range, kappa(-1), with a maximum at kappasigma approximately 10, implying an island of coexistence in the kappa-rho plane. The system...

The Poisson–Boltzmann (PB) equation is used to investigate effective colloid-interface interactions and the phase behavior of charge-stabilized colloidal suspensions. When a colloidal particle, immersed in an electrolyte, approaches an interface, which may be neutral (such as air) or charged (like electrodes, glass, etc.), image charge effects plus the deformation of the colloidal ion atmospher...

The application of intense ultrasound to a liquid-gas interface results in the formation of an ultrasonic fountain and generates both mist and vapor from the liquid. Here, the composition of the vapor and aerosol above an ultrasonic fountain is determined as a function of irradiation time and compared with the results of sparging for five different solutions. The experimental apparatus for dete...

Recent research has witnessed rapid advances in synthesis of nanocrystals, which has led to the development of a large variety of approaches for producing nanocrystals with controlled dimensions. However, most of these techniques lack the high-throughput production. Herein, we report on a viable and robust strategy based on an inert-gas-driven microflow reactor for continuous crafting of high-q...