In this paper it is shown that the charge transfer kinetics of the oxidation of sodium dithionite at a gold electrode in alkaline solution can be increased by modifying this electrode with cobalt(II)tetrasulfonated phthalocyanine, sodium salt (CoTSPc) or 5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin cobalt(II), tetrasodium salt (CoTSPor). Electrodeposition of these catalysts is discussed as ...

In this study, the preparation of some novel metallophthalocyanine (MPcs) complexes substituted with octakis(mercaptopropylisobutyl-POSS) functional group was achieved. By the reaction of [1-(3-mercapto)propyl-3,5,7,9,11,13,15-isobutylpentacyclo[9.5.1.1(3,9).1(5,15).1(7,13)]octasiloxane 1 with 4,5-dichloro-1,2-dicyanobenzene 2 in THF as the solvent in the presence of K2CO3 as the base, the phth...

We investigated the inhomogeneous distribution of concentration and electronic structure of the nitrogen (N) atoms doped in the multiwalled carbon nanotubes (CNTs) by variable-energy X-ray photoelectron spectroscopy (XPS), X-ray absorption near-edge structure, and electron energy-loss spectroscopy. The vertically aligned N-doped CNTs on the substrates were grown via pyrolysis of iron phthalocya...

Free 4-undecenoxyphthalocyanine molecules were covalently bonded to Si(100) and porous silicon through thermic hydrosilylation of the terminal double bonds of the undecenyl chains. The success of the anchoring strategy on both surfaces was demonstrated by the combination of X-ray photoelectron spectroscopy with control experiments performed adopting the commercially available 2,3,9,10,16,17,23,...

The experimental determination of formation constant for interaction of two water soluble phthalocyanines, Cobalt (II) 4,4',4",4'"-tetrasulpho phthalocyanine (CoTsPc ) and Manganese(II) 4,4',4",4"-tetrasulpho phthalocyanine (MnTsPc ) , with calf thymus DNA have been studied by UV-Vis spectrophotometric method at lrnM phosphate buffer , pH 7.4 and at 5 different temperatures 20,25,30,35 and 400 ...

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Related Articles Space-charge-limited currents in polyimide films Appl. Phys. Lett. 101, 242905 (2012) Flexible cobalt-phthalocyanine thin films with high charge carrier mobility Appl. Phys. Lett. 101, 222102 (2012) Analysis of mobile ionic impurities in polyvinylalcohol thin films by thermal discharge current and dielectric impedance spectroscopy AIP Advances 2, 042152 (2012) Dependence of con...

A rapid, simple and stable biosensor for aspartame detection was developed. Alcohol oxidase (AOX), carboxyl esterase (CaE) and bovine serum albumin (BSA) were immobilised with glutaraldehyde (GA) onto screen-printed electrodes modified with cobalt-phthalocyanine (CoPC). The biosensor response was fast. The sample throughput using a flow injection analysis (FIA) system was 40 h⁻¹ with an RSD of ...

Related Articles Space-charge-limited currents in polyimide films Appl. Phys. Lett. 101, 242905 (2012) Conductivity enhancement of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) films post-spincasting J. Appl. Phys. 112, 113709 (2012) Flexible cobalt-phthalocyanine thin films with high charge carrier mobility Appl. Phys. Lett. 101, 222102 (2012) Analysis of mobile ionic impurities in p...

Metal phthalocyanine, a synthetic porphyrin-like compound, has several applications in catalysis. Supported metal phthalocyanine catalysts have attracted increasing attention. In this study, glutaraldehyde (GA) was used for modifying polyvinyl alcohol (PVA) nanofibers by acetalization to improve the water resistance. Subsequently, cobalt tetra (2,4-dichloro-1,3,5-triazine) aminophthalo-cyanine ...