an ion imprinted polymer (iip) based on aniline-formaldehyde was synthesized and then modified with extra aniline as cross-linker in the presence and absence of sr (ii) as the template to produce ion imprinted poly(aniline-formaldehyde) (iipaf) and non imprinted poly(aniline-formaldehyde) (nipaf). the sorbent was characterized by fourier transform infrared spectroscopy and was used for solid ph...

background: the analysis of heavy metals at trace level is one of the main toxicologists concern, due to their vital rules in human`s life. cadmium is one of these toxic heavy metals, which released to the environment from various industries. methods: in order to determine cd (ii) ions in various matrices magnetic ion-imprinted polymer (iip) method has been developed and applied. this nano-sorb...

a pvc membrane ni(ii) ion selective electrode has been constructed using (1e,2e)-bis(2-aminophenyl)n'1,n'2-dihydroxyethanebis as membrane carrier. the electrode exhibited a goodpotentiometric response for ni(ii) over a wide concentration range 1.0×10-4 to 1.0×10-1m with aslope of 29.4±0.5 mv/decade a and a working ph range of 6.5-9.0. it had a fast response time of≤20s. the best performance was...

a pvc membrane ni(ii) ion selective electrode has been constructed using (1e,2e)-bis(2-aminophenyl)n'1,n'2-dihydroxyethanebis as membrane carrier. the electrode exhibited a goodpotentiometric response for ni(ii) over a wide concentration range 1.0×10-4 to 1.0×10-1m with aslope of 29.4±0.5 mv/decade a and a working ph range of 6.5-9.0. it had a fast response time of≤20s. the best perfo...

in order to study the cu(ii) ion selective electrode, an optimized membrane was prepared by mixing of 30 mg of pvc powdered, 5 mg of considered ionophore, 60 mg of plasticizer and 5 mg of additive. the sensor showed a near nernstian response for cu(ii) ions over a concentration range from 1.0×0-6 –1.0×0-2 m with a slope of 28.90.5 mv per concentration decade with a working ph range of 3.5-6.3. ...

The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro-acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa-hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(-) ion in the equatorial plane and one O atom from the trichloro-acetate ligand and one phenanthroline N ...

Four pentacoordinate Co( ii ) based single ion magnets were prepared and their structural, spectral, static dynamic magnetic properties analysed in detail.

Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(I1) form metallocarbonic anhydrases containing these metal ions at the same binding site. Of this series, only the Zn(I1) and Co(I1) enzymes catalyze the hydration of CO2 and the hydrolysis of p-nitrophenyl acetate. Likewise, only Zn(I1) and Co(I1) induce the metal ion-dependent binding of 3H-acetazolamide at the active center. Acetate, azi...

Four Schiff bases (H2L1 to H2L4) were synthesized by the condensation of o-aminophenol and unsaturated diketones (1,5-diarylpent-4-ene-1,3- -diones). Analytical, IR, 1H-NMR mass spectral data revealed their existence in imine?enamine form. Dibasic tetradentate coordination ML complexes (M = Cu(II), Ni(II), Co(II), Zn(II), Cd(II), Hg(II)) was established based on physical, analytical data. The f...