The artificial media have been of great interest in the communities of electromagnetic wave engineering including the fields of microwaves, milli-meter waves, optics etc. These are the fabricated aggregation structures composed of artificial molecules i.e. small objects which are designed to show required macroscopic electromagnetic characteristics. The sizes and spacings between the objects ar...

One of the problems encountered in CE separations of basic compounds is the adsorption of analytes onto the negatively charged capillary wall which could lead to poor repeatability of migration time and peak area. Additionally, separation of enantiomers of chiral of basic drugs is commonly carried out in low pH buffer which contributes to strong ionic interaction of the cationic drug ions with ...

Peptoids are oligomeric N-substituted glycines with potential as biologically relevant compounds. Helical peptoids provide an attractive fold for the generation of protein-protein interaction inhibitors. The generation of helical peptoid folds in organic and aqueous media has been limited to strict design rules, as peptoid-folding is mainly directed via the steric direction of alpha-chiral side...

An important property of electromagnetic fields, which arises from the interaction between fields and chiral molecules, is called optical chirality. By enhancing this field property, while maintaining constant input power, we are able to increase absorption of circularly polarized light by chiral molecules of a certain handedness. This enhancement is achieved through the use of achiral plasmoni...

One of the problems encountered in CE separations of basic compounds is the adsorption of analytes onto the negatively charged capillary wall which could lead to poor repeatability of migration time and peak area. Additionally, separation of enantiomers of chiral of basic drugs is commonly carried out in low pH buffer which contributes to strong ionic interaction of the cationic drug ions with ...

Transmission properties of chiral metamaterials are investigated through the loss factor. Besides the amplitudes of transmission coefficients of right and left circularly polarized waves, the phases are the other main keys to control the refractive index and chirality of the chiral media, directly affecting the loss factor (LF). The LF is low when the phase combination of circular waves is larg...

Enantioselective catalytic allylic alkylation for the synthesis of 2-alkyl-2-allylcycloalkanones and 3,3-disubstituted pyrrolidinones, piperidinones and piperazinones has been previously reported by our laboratory. The efficient construction of chiral all-carbon quaternary centers by allylic alkylation was previously achieved with a catalyst derived in situ from zero valent palladium sources an...

We study the no reflection condition for a planar boundary between vacuum and an isotropic chiral medium. In general chiral media, elliptically polarized waves incident at a particular angle satisfy the no reflection condition. When the wave impedance and wavenumber of the chiral medium are equal to the corresponding parameters of vacuum, one of the circularly polarized waves is transmitted to ...

This paper describes the development and optimization of chiral, nonpolar media with large second-order nonlinear optical responses. We employ molecular engineering, quantum-mechanical sum-over-states theory, and measurements of molecular hyperpolarizability by means of Kleinman-disallowed hyper-Rayleigh scattering in order to understand molecular properties. Then we analyze the appropriate arr...

In this work we apply field regularization techniques to formulate a number of new phenomena related to momentum induced by electromagnetic zero-point fluctuations. We discuss the zero-point momentum associated with magneto-electric media, with moving media, and with magneto-chiral media. PACS. 42.50.Lc Quantum fluctuations, quantum noise, and quantum jumps – 12.20.Ds Specific calculations – 3....