The direct conversion of methane to C2 hydrocarbons, in a quartz tube reactor enforced by a DC corona discharge, was investigated at atmospheric pressure. The process was carried out in the presence of metal oxide catalysts of Mn/W/SiO2, Mn/W/SiO2 (tetraethyl orthosilicate, TEOS), and Mn/W/CNT (supported on carbon nanotubes). The total yield to C2 hydrocarbons in the presence of metal oxide cat...

Catalytic hydrolysis technology of carbonyl sulfide (COS) at low temperature was reviewed, including the development of catalysts, reaction kinetics, and reaction mechanism of COS hydrolysis. It was indicated that the catalysts are mainly involved metal oxide and activated carbon. The active ingredients which can load on COS hydrolysis catalyst include alkali metal, alkaline earth metal, transi...

This study compared the prevalence of asthma with climate and air pollutant data to determine the relationship between asthma prevalence and these factors. We conducted a nationwide survey of respiratory illness and symptoms in middle-school students in Taiwan. Lifetime prevalences of physician-diagnosed asthma and of typical symptoms of asthma were compared to air monitoring station data for t...

During the summer of 2009, concentrations of oxides of nitrogen (NOx), oxides of sulphur (SOx), suspended particulate matter (SPM) and carbon monoxide (CO) were collected over successive periods of about 8 hour at eight sites. High volume air sampler was used to measure the concentration of oxides of nitrogen (NOx), oxides of sulphur (Sox), suspended particulate matter (SPM) and CO monitor was ...

ITIHEORETICAL considerations and experimental findings point out that reduction of iron oxides and I ores by carbon proceed via the gas' phase, whenever the latter is present. The overall reaction is a coupling of the following two component reactions, viz., Gasification of carbon C(S) CO2 (g) = 2C0 (g) and Reduction of iron oxide mFe.0y(S) -fCO (g) = nFezOw [S) CO2 (g) ' Recent kinetic studies...

The catalytic asymmetric phospha-Michael reaction of dialkyl phosphine oxides with β,β-disubstituted α,β-unsaturated carbonyl compounds was achieved. The products bearing tetrasubstituted carbon stereocenters were obtained in high yields with excellent enantioselectivities (up to >99% ee).

Full-potential density-functional calculations show that the electronic structure of one-dimensional ferrimagnetic Ca3Co2O6 varies from metal to half metal to insulator as its magnetic ordering changes from the ferrimagnetic through the ferromagnetic to the paramagnetic state. The present Letter is the first to establish the occurrence of half metallicity in one-dimensional oxides. Moreover, th...

In addition to summarizing the main thrusts of each paper presented at this Discussion, other urgent issues involving the role (and characterization) of new catalysts for eliminating oxides of nitrogen, for using CO2 liberated from steel mills, for fuel cells and the need for rapid decarbonization of fossil fuels are outlined.This article is part of a discussion meeting issue 'Providing sustain...