Amorphous sulfated zirconium hydroxide was promoted with iron or manganese via the incipient wetness technique, to give 0.5–3.5 weight% promoter in the final catalyst. An exothermic reaction during the calcination temperature ramp (to 823 or 923 K) leads to a rapid overheating (“glow”) of the sample. XRD shows that crystallization starts before and progresses during the overheating. The surface...

nano-structured lanthanum strontium cobalt ferrite, la0.6sr0.4co0.2fe0.8o3 (lscf), was successfully synthesized via co-precipitation method using metal nitrates as starting materials. effects of precipitating agent and calcination temperature on the phase composition and morphology of synthesized powders were systematically studied using x-ray diffraction (xrd) and field emission scanning elect...

Attrition of six different limestones was studied during calcium looping cycles for CO2 capture in a lab-scale fluidized bed apparatus. The tests were carried out under realistic conditions representative of a process with calcination in an oxy-firing environment. The focus of the activity was to investigate the effect of the presence of SO2 both in the calcination and in the carbonation stages...

a novel nano – sized  manganese (ii) coordination polymer, [{mn(ncs)2(l)(h2o)2}(l)]n  , (1) (l- = 4,4'-bipyridine), have been synthesized by a sonochemical process and characterized by scanning electron microscopy (sem), x-ray diffraction (xrd), ir spectroscopy and elemental analysis.  direct calcination of the single crystals and nano-sized compound 1 at 400 0c under air atmosphere yields...

The interaction of vanadium oxide and niobium oxide with A1203 and TiO2 supports is examined with Raman spectroscopy. The Raman spectra of the supported metal oxides reveal that the strong interaction of the metal oxides with AI203 and TiO2 supports results in the formation of two-dimensional surface metal oxide overlayers. The surface vanadium oxide overlayers are unstable to high calcination ...

A one-dimensional mathematical model was developed for the simulation of limestone calcination in rotary kilns. The model is comprised of ordinary differential equations derived from mass and energy conservation principles. The system of equations is solved by a fourth-order Runge-Kutta method. The model predicts, in the axial direction, temperature profiles for the bed of particles, the gas ph...

Mesostructured nickel oxide was formed with nickel sulfate and cationic surfactant cetyltrimethylammonium bromide (CTAB). X-ray diffraction (XRD) peaks at low scattering angles and transmission electron microscopy (TEM) indicated that a mesostructure was formed. However, these XRD patterns disappeared after calcination. The addition of sodium silicate in the precursor solutions produced a mesos...

Recycled chicken eggshells after calcination have been used as a nonconventional heterogeneous catalyst for biodiesel synthesis from karanja oil from the pongam tree (Pongamia pinnata). The catalyst was characterized on X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and differential thermal analysis/thermogravimetric analysis (DTA/TGA). The formation of the calcium oxi...