Single-walled boron nitride nanotubes are chosen as model reactants, and (10,0) and (6,6) are chosen as representatives of armchair and zigzag nanotubes, respectively, to study the interaction of carbenes of the type :CX2. It is found that, contrary to the case of carbon nanotubes, boron nitride tubes, particularly armchair BNNTs, do not show a propensity for cyclopropane ring formation. The SW...

Understanding the coupling between one-dimensional (1D) materials and their protective is essential for developing nanodevices. Herein, we investigate effect of size, chirality, type nanotubes [such as carbon/boron nitride (CNTs/BNNTs)] on atomic electronic structures confined Te chains using density functional theory. We find that optimal configurations in CNTs/BNNTs depend strongly size but w...

We have created insulated C60 nanowire by packing C60 molecules into the interior of insulating boron nitride nanotubes (BNNTs). For small-diameter BNNTs, the wire consists of a linear chain of C60 molecules.With increasing BNNT inner diameter, unusual C60 stacking configurations are obtained (including helical, hollow core, and incommensurate) that are unknown for bulk or thin-film forms of C6...

Noncovalent functionalization of boron nitride nanotubes (BNNTs) in aqueous solution was achieved by means of pi-stacking of an anionic perylene derivative, through which carboxylate-functionalized BNNTs were prepared for the first time. Starting from the functionalized nanotubes, an innovative methodology was designed and demonstrated for the controlled near-surface carbon doping of BNNTs. As ...

We report the fabrication of and investigations into the dielectric and thermal properties of epoxy/boron nitride nanotube (BNNT) composites. It was found that BNNT fillers can effectively adjust the dielectric constant of epoxy. Moreover, the thermal conductivity of epoxy was improved by up to 69 % with 5 wt % BNNTs. Our studies indicate that BNNTs are promising nanofillers for polymers, to ob...

For the first time, patterned growth of boron nitride nanotubes is achieved by catalytic chemical vapor deposition (CCVD) at 1200 C using MgO, Ni, or Fe as the catalysts, and an Al2O3 diffusion barrier as underlayer. The as-grown BNNTs are clean, vertically aligned, and have high crystallinity. Near band-edge absorption ∼6.0 eV is detected, without significant sub-band absorption centers. Elect...

The use of composite materials increases due to its exceptionally better mechanical properties compared to their individual constitutes. The use of Nano materials as one of the constitutes of composite materials adds the advantages specially of high dynamic behavior due to their dimensions of nano scale. The carbon nanotubes (CNTs) and boron nitride nanotubes (BNNTs) possess excellent mechanica...

A series of boron nitride nanotubes (BNNTs)/ carbide (B4C) composite ceramics were prepared using spark plasma sintering (SPS) technology, which uses B4C powders as the matrix and BNNTs toughening phase. X-ray diffraction (XRD) scanning electron microscope (SEM) then used to characterize ceramic samples. The effects temperature, content, particle size on microstructure mechanical properties inv...

The adsorption of H2O, NH3 and HCOOH as polar probe molecules and C6H6 and CH4 as non-polar ones on a series of zig-zag (n,0) single-walled boron nitride nanotubes (BNNTs) and on a boron-nitride mono-layer (BNML) has been studied by means of B3LYP-D* periodic calculations. Computed electrostatic potential maps for the pristine BN nanomaterials indicate that the smaller the radius, the larger th...

Methane adsorption onto single-wall boron nitride nanotubes (BNNTs) and carbon nanotubes (CNTs) was studied using the density functional theory within the generalized gradient approximation. The structural optimization of several bonding configurations for a CH4 molecule approaching the outer surface of the (8,0) BNNT and (8,0) CNT shows that the CH4 molecule is preferentially adsorbed onto the...