We synthesize a series of block copolymers comprising a polystyrene (PS) block and an imidazolium-functionalized PS (IL) block and characterize their assembly properties. We use small-angle neutron scattering and dynamic light scattering to determine the micelle size and shape in dilute solutions and to assess the micelle interactions in concentrated solutions. By studying a series of copolymer...

Efficient, one-pot preparation of synthetically challenging, high molecular weight (MW), narrowly dispersed brush block copolymers and random copolymers in high conversions was achieved by ring-opening metathesis (co)polymerization (ROMP) of various macromonomers (MMs) using the highly active, fast-initiating ruthenium olefin metathesis catalyst (H(2)IMes)(pyr)(2)(Cl)(2)RuCHPh. A series of rand...

We investigate the complexation of ampholytic poly(N-isopropylacylamide)-block-poly- (L-glutamic acid)-block-poly(L-lysine) (PNiPAM-b-PLG-b-PLLys) triblock copolymers and PNiPAM-block-(PLG-co-PLLys) diblock copolymers with counter charged anionic and cationic surfactants. Both triblock and diblock copolymers are able to selectively form complexes through either L-glutamic acid-cationic surfacta...

The synthesis of a series of new rod-coil diblock copolymers with different molecular weights and low polydispersity was achieved by atom transfer radical polymerization. The block architecture (coil-conformation of styrene segment and rigid-rod conformation of 2,5-bis[(4-methoxyphenyl)-oxycarbonyl]styrene segment) of the diblock copolymers was experimentally confirmed by proton nuclear magneti...