In this paper we present the application of carbon nanotubes as unique sorbents for the fabrication of microtraps for the nanoscale adsorption/desorption of relatively large semivolatile organic molecules. The microtrap application requires high adsorption capacity as well as easy desorbability; the latter being critical for semivolatile compounds. The sorbent characteristics of single and mult...

Using a path integral technique, we show exactly that for a semiflexible biopolymer in constant extension ensemble, no matter how long the polymer and how large the external force, the effects of short-range correlations in the sequence-dependent spontaneous curvatures and torsions can be incorporated into a model with well-defined mean spontaneous curvature and torsion as well as a renormalize...

Steam hydration has been proposed as a suitable technique for improving the performance of CaO as a regenerable sorbent in CO2 capture systems. New hydration experiments conducted in this study, confirm the reported improvements in the capacity of sorbents to carry CO2. An examination of the textural properties of the sorbent after hydration and mild calcination revealed a large increase in the...

This field study evaluated the ability of a multi-sorbent sampling tube/thermal desorption technique to identify and to provide quantitative data on volatile organic contaminants in indoor air. Air samples, from 12 Canadian homes, were collected on multilayer sorbent cartridges and analyzed using Adsorption/Thermal Desorption coupled with Gas Chromatography/Mass Spectrometry. The study included...

The efficiency of four low-cost sorbent materials namely peas husk, broad bean husk, medlar peel and fig leaves, for removing cadmium ions from aqueous solutions, in single systems, has been investigated in batch mode. Kinetic data and equilibrium sorption isotherms were measured. Kinetics of cadmium sorption was contact time, initial cadmium concentration and sorbent type dependent. For a give...

The case of a sorption process considered here involves a solid phase (sorbent) and a liquid phase (solvent, normally water) containing a dissolved species to be sorbed (sorbate, e.g. metal ions). Due to the higher ‘affinity’ of the sorbent for the sorbate species the latter is attracted into the solid and bound there by different mechanisms. This process takes place until an equilibrium is est...

This study presents the development of a novel calcium-oxide sorbent for carbon dioxide capture. In this work, CaO sorbent was impregnated with different molar percentage of titanium ethoxide. The sorbent prepared with 50 % of titanium ethoxide resulted in the best uptake characteristics for CO2. Compared to others, a higher BET surface area and a larger pore volume were observed. An excellent ...

Activated carbon is known to adsorb aqueous Hg(II). MPAC (magnetic powdered activated carbon) has the potential to remove aqueous Hg to less than 0.2 μg/L while being magnetically recoverable. Magnetic recapture allows simple sorbent separation from the waste stream while an isolated waste potentially allows for mercury recycling. MPAC Hg-removal performance is verified by mercury mass balance,...

Methods to monitor contamination of workplaces with antineoplastic drugs have been developed and validated. Cyclophosphamide (CP) was used as a model compound as it is one of the most commonly used antineoplastic drugs. A wipe sampling method to detect contamination with CP at surfaces was developed. A personal air sampling method to sample gas and vapour on solid sorbent tubes and particles wi...

......................................................................................................................................................................................... 1 1.0 INTRODUCTION ....................................................................................................................................................................... 2 2.0 COMMERCIAL SORBENT...