نتایج جستجو برای: benzylation
تعداد نتایج: 207 فیلتر نتایج به سال:
Significance The manipulation of proteins in a site-selective manner underpins much modern protein chemistry. A careful evaluation selenomethionine benzylation led to the identification highly efficient bromobenzyl linker for bioconjugation. This selenonium-forming ligation reaction can efficiently link other complex molecules such as synthetic peptides, polymers, or reactive handles. selenoniu...
4.2.8. Reductive Coupling 3109 5. Reaction of Aromatic Compounds 3110 5.1. Electrophilic Substitutions 3110 5.2. Radical Substitution 3111 5.3. Oxidative Coupling 3111 5.4. Photochemical Reactions 3111 6. Reaction of Carbonyl Compounds 3111 6.1. Nucleophilic Additions 3111 6.1.1. Allylation 3111 6.1.2. Propargylation 3120 6.1.3. Benzylation 3121 6.1.4. Arylation/Vinylation 3121 6.1.5. Alkynylat...
A photochemical organocatalytic strategy for the direct enantioselective β-benzylation of α,β-unsaturated aldehydes is reported. The chemistry capitalizes upon the light-triggered enolization of 2-alkyl-benzophenones to afford hydroxy-o-quinodinomethanes. These fleeting intermediates are stereoselectively intercepted by chiral iminium ions, transiently formed upon condensation of a secondary am...
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