The separation of small molecule gases by membrane technologies can help performance enhancement and process intensification for emerging advanced fossil energy systems with CO2 capture capacity. This paper reports the demonstration of controlled modification of zeolitic channel size for the MFI-type zeolite membranes to enhance the separation of small molecule gases such as O2 and N2. Pure-sil...

The development of lowand hightemperature alteration products in a 23 m section of ocean-floor basalts is described. Analcime, calcite and dioctahedral smectite are ubiquitous. Trioctahedral smectite, smectite-chlorite mixed layers, chabazite and scolecite occur in the deeper sections with Fe 3+ oxides/ hydroxides progressively becoming more abundant in the upper regions. The upper layers of th...

In this study, organic amines were used to modify zeolite NaA and analcime synthesized using fly ash iron tailing slag as raw materials, respectively, the adsorption properties of modified zeolites toward CO2 determined. We found that when tetraethylenepentamine (TEPA) was used, had highest nitrogen content. The capacity for 4.02 mmol/g 1.16 temperature 70 °C flow rate 50 mL/min. According isot...

A PEBAX-nano zeolite X mixed matrix membrane was fabricated and operationally characterized using single gas (CO2) permeation. X-ray diffraction (XRD) analysis was used to study the arrangement of polymer chains of mixed matrix membrane. The membranes were characterized by scanning electron microscopy (SEM) to study cross-sectional morphology. The single gas permeability were carried...

in the present work, b-zsm-5 zeolite membranes were synthesized on porous tubular α-alumina supports by several subsequence in situ crystallization hydrothermal treatments. the tio2- bohmite and ɣ- alumina intermediate layers were applied to improve the lattice matching between zeolite layer and the support. the uniform membrane intermediate layers with low permeation resistance were prepared o...

1. Introduction 1. Introduction Information on mass transport in polycrystalline zeolite membranes is necessary for a theoretical estimation of the membrane performances. Zeolite membranes are usually prepared as thin layer of an assembly of small zeolite crystals including many intercrystalline regions. Thus, the intercrystal region would influence their individual diffusion properties, which ...

ABSTRACT Located in the southwest corner of Ratanakiri Volcanic Province, Wat Ocheng basalt is first known zeolite locality Cambodia. The a fine-grained, vesicular to amygdaloidal, subalkaline transitional alkaline intraplate tholeiite comprised 30% lath-like plagioclase (average: Ab51An45Or4), 35% interstitial augite Wo44En35Fs21), 25–30% zeolites after and volcanic glass, minor skeletal ulvös...

We have conducted large-scale screening of zeolite materials for CO2/CH4 and CO2/N2 membrane separation applications using the free energy landscape of the guest molecules inside these porous materials. We show how advanced molecular simulations can be integrated with the design of a simple separation process to arrive at a metric to rank performance of over 87,000 different zeolite structures,...