Crystalline mesoporous molecular sieves have long been sought as solid acid catalysts for organic reactions involving large molecules. We synthesized a series of mesoporous molecular sieves that possess crystalline microporous walls with zeolitelike frameworks, extending the application of zeolites to the mesoporous range of 2 to 50 nanometers. Hexagonally ordered or disordered mesopores are ge...

Ge(2)Sb(2)Te(5) (GST) is a technologically very important phase-change material that is used in digital versatile disks-random access memory and is currently studied for the use in phase-change random access memory devices. This type of data storage is achieved by the fast reversible phase transition between amorphous and crystalline GST upon heat pulse. Here we report pressure-induced reversib...

the nanocrystallization of co67fe4cr7si8b14 amorphous ribbons which prepared by planar flow melt spinning process (pfms) was investigated. crystallization of the ribbons was studied by differential thermal analysis (dta), x-ray diffraction (xrd) and transmission electron microscopy (tem). the dta result of amorphous ribbon at heating rate of 10˚c/min showedoccurrence of phase transitions in two...

For plastic waste cracking the path for production of high olefins yield without loose in gasoline fraction is an intriguing option. Among commercial FAU zeolites different properties and mesoporous HAlMCM-48 materials, catalysts polypropylene (PP) being able to operate low-temperature regime was searched. The aim investigate effects presence mesopore system context internal external acidic fea...

During thermal oxidation of binary amorphous AlxZr1-x solid solutions over wide alloycomposition (0.26 ≤ x ≤ 0.68) and oxidation-temperature (350 °C – 560 °C) ranges, a single amorphous ternary oxide phase of well-defined stoichiometry, (Al0.33Zr0.67)O1.83, emerges. The composition of this unexpectedly stoichiometric ternary amorphous oxide phase, that develops instead of the crystalline oxide ...

Infrared absorption measurements of amorphous and crystalline nanoparticles of GeTe reveal a localized surface plasmon resonance (LSPR) mode in the crystalline phase that is absent in the amorphous phase. The LSPR mode emerges upon crystallization of amorphous nanoparticles. The contrasting plasmonic properties are elucidated with scanning tunneling spectroscopy measurements indicating a Burste...

Systematic studies of pressure-induced amorphization of natrolites (PIA) containing monovalent extra-framework cations (EFC) Li(+), Na(+), K(+), Rb(+), Cs(+) allow us to assess the role of two different EFC-H2O configurations within the pores of a zeolite: one arrangement has H2O molecules (NATI) and the other the EFC (NATII) in closer proximity to the aluminosilicate framework. We show that NA...

The structures and magnetic properties of Pr–Fe–Al alloys produced by the metallic mold casting method were investigated. The Pr–Fe–Al alloy consisted of the amorphous phase together with the non-ferromagnetic Pr phase. Magnetic measurements confirmed that the origin of coercivity in the alloys was the amorphous phase. It was found that the Curie temperature and coercivity of the alloys were st...