The metal-insulator transition (MIT) caused purely by alloy disorder in a Zno 3Cdo 7Se semiconductor alloy has been probed by using persistent photoconductivity. Key parameters that describe the MIT, including the critical electron concentration n, and the energy tail states distribution parameter Eo, have been determined experimentally. Our results, together with those obtained for impurity-do...

Crystallization of α – Fe phase during annealing process of Fe55Cr18Mo7B16C4 bulk amorphous alloy has been evaluated by X- ray diffraction, differential scanning calorimetric tests and TEM observations in this research. In effect, crystallization mechanism and activation energy of crystallization were evaluated using DSC tests in four different heating rates (10, 20, 30, 40 K/min). A two -st...

Microstructure of a rapidly solidified Al-4V-2Fe alloy has been examined in detail by means of transmission electron microscopy and atom probe field ion microscopy. It is composed of a mixture of α-Al and amorphous phases. α-Al grains are relatively large (400 nm), but nanoscale domains of amorphous phase are trapped in the fcc grains. The interface between the α-Al and amorphous phases are ver...

Hole drift mobilities have been measured using photocarrier time-of-l-light for several hydrogenated amorphous silicon-carbon alloy specimens. We find that, as the band gap increases, the hole drift mobility remains essentially constant. The temperature and dispersion properties were broadly consistent with hole multiple trapping in the valence bandtail. In conjunction with previous drift mobil...

2014 Partial interference functions and radial distribution functions are determined using the anomalous X-ray diffraction technique for the amorphous alloy Cu2Y. These results are generalized for the amorphous family of A2B amorphous alloys where A is Co, Fe, Cu, or Ni and B is Zr or Y. By comparing the coordination number and interatomic distances obtained experimentally with those of geometr...

in this research, mechanical alloying was used to produce ti-50al, ti-45al-5cr and ti-45al-5w (at%) alloys. the effect of ternary addition (cr and w) on microstructure and production efficiency of tial alloy were investigated. alloying was performed in a planetary mill and the milling time varying from 5 to 70h. the structural evaluation in these powders was done by x-ray diffraction (xrd) tech...

Bulk metallic glasses (BMGs) have received a great deal of attention due to scientific and technological interest ever since the first successful synthesis of an amorphous phase in the Au–Si system in 1960 (Klement et al., 1960). There has been a lot of interest to identify parameters to assess the glass forming ability (GFA) of various alloy systems and compositions. A great deal of scientific...

Nanosized amorphous alloy powders of Fe20Ni80 , Fe40Ni60 , and Fe60Ni40 were prepared by sonochemical decomposition of solutions of volatile organic precursors, Fe~CO!5 and Ni~CO!4 in decalin, under an argon pressure of 100 to 150 kPa at 273 K. Magnetic susceptibility of Fe40Ni60 and Fe60Ni40 indicates blocking temperatures of 35 K and a magnetic particle size of about 6 nm. Thermogravimetric m...

In lithium-ion batteries, the electrochemical reaction between the electrodes and lithium is a critical process that controls the capacity, cyclability and reliability of the battery. Despite intensive study, the atomistic mechanism of the electrochemical reactions occurring in these solid-state electrodes remains unclear. Here, we show that in situ transmission electron microscopy can be used ...

Graphene aerogels (GAs) are functionalized with Fe-Co-P alloy using an electro-deposition method. The Fe-Co-P alloy coated on the graphene nanosheets is found to possess an amorphous structure and a nanoporous architecture of GAs. The electro-mechanical properties of GAs are significantly affected by the Fe-Co-P nanoparticles embedded inside GAs. The electro-mechanical responses of GA/Fe-Co-P n...