A ytterbium doped active material for thin-disk laser was developed based on aluminosilicate and phosphosilicate glass matrices containing up to 30 mol% YbO1.5. Thick films and bulk samples were prepared by sol-gel processing. The structural nature of the base material was assessed by X-ray diffraction and Raman spectroscopy and the film morphology was evidenced by scanning electron microscopy....

Porous silicates containing dilute amounts of tri-, tetra- and penta-valent metal sites, such as TS-1, Sn-β and Fe-ZSM-5, have recently emerged as state of the art catalysts for a variety of sustainable chemical transformations. In contrast with their aluminosilicate cousins, which are widely employed throughout the refinery industry for gas-phase catalytic transformations, such metallosilicate...

The flexibility window in zeolites was originally identified using geometric simulation as a hypothetical property of SiO2 systems. The existence of the flexibility window in hypothetical structures may help us to identify those we might be able to synthesize in the future. We have previously found that the flexibility window in silicates is connected to phase transitions under pressure, struct...

Recent studies have shown that the mullitization of diphasic aluminosilicate matrices comprising transitional alumina and amorphous silica occurs via a nucleation and growth process. Nucleation is preceded by a temperature-dependent incubation period. Following this incubation period, rapid nucleation of mullite occurs, producing about 1.8 X 10" nuclei/cm3, which remains constant throughout the...

The possibility of supplementing livestock diets with an aluminosilicate to protect them from fescue toxicosis was investigated. An in vitro study showed that hydrated sodium calcium aluminosilicate (HSCAS) removed greater than 90% of the ergotamine from aqueous solutions at pH 7.8 or lower, indicating a high affinity of ergotamine for HSCAS in vitro. Rats fed diets containing tall fescue seed ...

The aim of this report is to extend understanding and capability for linking atomistic understanding of glass corrosion mechanisms to continuum models of reaction and transport in the subsurface environment. The focus of this report is on aluminosilicate glass dissolution supported by studies on natural aluminosilicate minerals which exhibit similar corrosion properties. The ultimate objectives...

Presented here is a heterometallic organic framework [Na(2)(H(2)O)(10)](n)[CuZn(4)(mu(3)-OH)(4)(btec)(2)](n).2nH(2)O (1, btec = 1,2,4,5-benzenetetracarboxylate) that incorporates mixed Cu(2+)-Zn(2+) oxide chains and accommodates Na(+) cations as extraframework guest species; such a building mode is comparable to that of aluminosilicate zeolites where the porous framework combines two kinds of s...

Precursors derived from the hydrolysis of organic or inorganic salts have been widely used to produce ceramic coatings for a broad variety of applications. When applying the liquid precursors to the substrates, it is extremely challenging to control the film uniformity and homogeneity. The rate of solvent evaporation at different locations is different, causing the viscosity variation and flows...

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Available online 31 August 2010