The reaction of [Rh(μ-Cl)(cod)]2 with diimines, differing in their steric and electronic properties, diphenylphosphine oxide leads to the oxidative addition products, hydrido-phosphinito-Rh(III) complexes {Rh(PPh2OH)(PPh2O)(NN)(H)Cl} (1), stabilized by formation a hydrogen bonded phosphinous acid-phosphinito quasi-chelate [(PO⋅⋅⋅HOP)-κ2P]. Exchange hydride chloride afford {Rh(PPh2OH)(PPh2O)(NN)...

The title compound, [Rh(C(8)H(12))(C(18)H(36)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P-Rh-...

Several bis(hydrosulfido)-bridged dinuclear rhodium(I) compounds, [{Rh(mu-SH)(L)(2)}(2)], have been prepared from rhodium(I) acetylacetonato complexes, [Rh(acac)(L)(2)], and H(2)S(g). Reaction of [Rh(acac){P(OPh)(3)}(2)] with H(2)S(g) affords the dinuclear bis(hydrosulfido)-bridged compound [{Rh(mu-SH){P(OPh)(3)}(2)}(2)] (1). However, reaction of complexes [Rh(acac)(CO)(PR(3))] with H(2)S(g) gi...

Turgut, H., Mutman, D., Canakcioglu, N.G, Bayraktar, I., Tunc, (Eds.) (2022). Istanbul as an Endless Space of “Urban Articulation” (Sonsuz Bir “Kentsel Artikülasyon” Mekânı Olarak İstanbul), İstanbul, Özyeğin University Publication, ISBN 978-605-5625-22-1

The reaction of [Rh(μ-SH)(CO)(PPh(3))](2) or [Rh(μ-SH){P(OPh)(3)}(2)](2) with [Cp*MCl(2)](2) (M = Rh, Ir) in the presence of NEt(3) afforded the Rh(3) and IrRh(2) sulfido-bridged compounds [Cp*M(μ(3)-S)(2)Rh(2)(CO)(2)(PPh(3))(2)] (M = Rh, 1; Ir, 2) and [Cp*Rh(μ(3)-S)(2)Rh(2){P(OPh)(3)}(4)] (3). The reaction with [MCl(2)(cod)] (M = Pd, Pt), cis-[PtCl(2)(PPh(3))(2)] or [(η(6)-C(6)H(6))RuCl(2)](2)...

Binuclear rhodium(II) complexes [Rh(2)Cl(2)(mu-OOCR)(2)(N-N)(2)] {R = H, Me; N-N = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)} and [Rh(2)(mu-OOCR)(2)(N-N)(2)(H(2)O)(2)](RCOO)(2) (R = Me, Et;) have been synthesized and their structure and properties have been studied by electronic, IR and (1)H NMR spectroscopy. Antibacterial activity of these complexes against Escherichia coli and Staphyl...

In order to further enhance the Ni/Ce 0.8Gd0.2O2-δ (Ni/GDC20) cermet anodic performance for low temperature solid oxide fuel cell (LT-SOFC), a study was conducted on the nanostructuring of NiO/GDC composite by only once wet-infiltration of rhodium chloride precursor. By using electrochemical impedance spectroscopy (EIS) analysis, the effect of only one drop of Rh-infiltrating solution on ...

Microcentrifuge tubes containing 8 x 10(6) purified oocysts of Cryptosporidium parvum suspended in 400 microliters of deionized water were stored at 5 degrees C for 168 h or frozen at -10, -15, -20, and -70 degrees C for 1 h to 168 h and then thawed at room temperature (21 degrees C). Fifty microliters containing 10(6) oocysts was administered to each of five to seven neonatal BALB/c mice by ga...

Objective(s):Helicobacter pylori infection occurs worldwide, but the prevalence of this infection varies greatly among different countries and population groups. The aim of this study was to determine the seroprevalence of anti-Helicobacter pylori and anti-cytotoxin-associated gene A (CagA) antibodies in asymptomatic healthy population in the center of Iran and to investigate the relation with ...