a series of cuo-zno-al2o3 nanoparticles over hzsm-5 were successfully prepared using different methods of batch co-precipitation, semibatch co-precipitation and combined co-precipitation-ultrasound. nitrates of copper, zinc and aluminum were used as precursors, while na-zsm-5 was employed as composite support and sodium carbonate was used as precipitant agent. the effects of preparation methods...

Graphene-encapsulated nickel nanoclusters are a feasible strategy to inhibit the deactivation of nickel-based catalysts. In this work, graphene-encapsulated catalysts (Ni@C/HZSM-5) were prepared by compression forming process, using pseudo-boehmite, Al2O3, and ZrO2 as binders. The pseudo-boehmite was gradually transformed from amorphous crystalline alumina at high temperatures, which destroyed ...

In order to reduce the harmful constituents in cigarette smoke, two hierarchical composites were synthesized. Based on, zeolites HZSM-5 or NaY fragments were introduced into the synthetic system of mesoporous silica SBA-15 or MCM-41 and assembled with the mesoporous materials. These porous composites combine the advantages of micro- and mesoporous materials, and exhibit higher effects than acti...

Hierarchical porous catalysts have recently attracted increasing interest because of the enhanced accessibility to active sites on such materials. In this context, previously reported hierarchically mesoporous ASN and ASPN materials are evaluated by applying them to the dehydration of glycerol, and demonstrate excellent catalytic performance. In addition, a comprehensive understanding of the ef...

The dynamics of N2O decomposition to gaseous nitrogen and oxygen over HZSM-5 catalysts with a low iron content (200 and 1000 ppm) was studied by the transient response method in the temperature range 523–653 K. The active catalysts were prepared from HZSM-5 with Fe in the framework on its steaming at 823 K followed by thermal activation in He at 1323 K. Two main steps were distinguished in the ...

Aromatics and cyclic-hydrocarbons are the significant components of jet fuel with high energy-density. However, conventional technologies for bio-fuel production cannot produce these products without further aromatization and isomerization. In this work, renewable liquid fuel with high content of aromatics and cyclic-hydrocarbons was obtained through aqueous catalytic conversion of biomass sorb...

Catalysts with a Zn/H+ molar ratio ranging from 0 (H-ZSM5) to 1.8 (Zn/H-ZSM5), were prepared by wet impregnation three commercial zeolites Si/Al of 15, 40 and 75. The texture, acidity reactivity the bifunctional catalysts characterized by: N2, IR followed adsorption pyridine NH3-TPD, tested at 500 °C low partial pressure ethylene (PC2H4 = 0.005 MPa) high GHSV (ca 13,300 h−1). intrinsic activity...