By the reaction of TBA(4)H(4)[γ-SiW(10)O(36)] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag(6)](4+) cluster, TBA(8)[Ag(6)(γ-H(2)SiW(10)O(36))(2)]·5H(2)O, could be synthesized, and the molecular structure was determined.

A numerical investigation has been executed in a curve-shaped enclosure crammed with hybrid nanofluid containing wavy-shaped inner cylinder the existence of magnetic field. mixture copper and alumina nanoparticles normal water-based solution is used to create nanofluid. The natural convective flow generated as result temperature difference between cold outer hot wavy cylinder. parametric examin...

nowadays green house gases such as carbon have the most effect on global climate changes that can be decreased by plant and soil carbon sequestration of rangelands. livestock grazing has high potential to decrease or increase carbon storage. so this research investigated the effects of enclosure on plant carbon storage in rangeland of enclosure (shah tappeh-chah mahmood) and no enclosure (chiro...

In this paper, we consider the derivation of the modified Wenzel’s and Cassie’s equations for wetting phenomena on rough surfaces from a three-dimensional phase field model. We derive an effective boundary condition by asymptotic two-scale homogenization technique when the size of the roughness is small. The modified Wenzel’s and Cassie’s equations for the apparent contact angles on the rough s...

We investigate, using the framework of Γ-convergence, a phase-field model proposed in [Torabi et al, Proc. R. Soc. A, 2009] for strongly anisotropic systems; in particular, we prove a full Γ-convergence result for an anisotropic Modica-Mortolatype energy.