PURPOSE Different types of tooth preparations influence the marginal precision of zirconium-oxide based ceramic single crowns. In this in vivo study, the marginal fits of zirconium-oxide based ceramic single crowns with vertical and horizontal finish lines were compared. MATERIALS AND METHODS Forty-six teeth were chosen in eight patients indicated for extraction for implant placement. CAD/CAM...

In recent years many works are aimed at finding a method of controllable switching between hydrophilicity and hydrophobicity of a surface. The hydrophilic surface state is generally determined by its energy. Change in the surface energy can be realized in several different ways. Here we report the ability to control the surface wettability of zirconium dioxide nano-coatings by changing the comp...

Zirconium-based alloys are used in water-cooled nuclear reactors for both nuclear fuel cladding and structural components. Under this harsh environment, the main factor limiting the service life of zirconium cladding, and hence fuel burn-up efficiency, is water corrosion. This oxidation process has recently been linked to the presence of a sub-oxide phase with well-defined composition but unkno...

Raman spectroscopy has been used as a local probe to characterize the structural evolution of magnetron-sputtered decorative zirconium oxynitride ZrOxNy films which result from an increase of reactive gas flow in the deposition The lines shapes, the frequency position and widths of the Raman bands show a systematic change as a function of the reactive gas flow (a mixture of both oxygen and nitr...

Purpose: The mechanical strength of polymethyl methacrylate (PMMA) remains far from ideal for maintaining the longevity of denture. The purpose of this study was to evaluate the effect of Zirconium oxide (ZrO2) nanofillers powder with different concentration (1.5%, 3%, 5% and 7%) on the flexural strength, fracture toughness, and hardness of heat-polymerized acrylic resin. Materials and methods:...

Zirconium oxide has found extensive applications in various industries becauseof its excellent properties such as high strength; high-temperature resistance;extraordinary wearing resistance; ionic conductivity; and corrosion resistance. Also, someProperties like high melting point, high mechanical and thermal strength, high dielectricconstant and low conductivity have in...

An overview on the developments of zirconium phosphate (ZrP) and its organic derivatives in heterogeneous catalysis in recent years is reported in the present review. Two basic aspects have been emphasized: first, the catalytic properties of zirconium phosphates were discussed, with particular attention to the effect of surface acidity and hydrophobic/hydrophilic character, textural properties,...

A low-cost and facile route to the synthesis of bimetallic glycolato zirconate (Na2Zr(C2H4O2)3) and homometallic glycolato cerate (Ce(C2H4O2)), which can be used as alkoxide precursors for sodium zirconium oxide (and/or zirconia by sol–gel process) and ceria materials, has been developed from the reaction of inexpensive starting materials via the oxide one-pot synthesis (OOPS) process. Both com...

Nanostructurally stabilized zirconium oxide (NSZ) hard transparent fi lms were produced without chemical stabilizers by the ion beam assisted deposition technique (IBAD). A transmission electron microscopy study of the samples produced below 150 °C revealed that these fi lms are composed of zirconium oxide (ZrO2) nanocrystallites of diameters 7.5 ± 2.3 nm. X-ray and selected-area electron diffr...

The aim of the current work is the synthesis and characterization of metallic Zr nanoparticles. The preparation is carried out by using the RAPET method (Reaction under Autogenic Pressure at Elevated Temperatures) developed in our lab. The RAPET reaction of commercial ZrO(2) with Mg powder was carried out in a closed stainless steel cell, at 750 °C. On completion of the reaction, the additional...