Treatment of tetrakis(diethylamido)zirconium(IV); [Zr(NEt2)4] with a series of β-ketoimines ({[RHN]C(CH3)=C(H)C(CH3)=O} where R is a functionalized side-chain; 4-(2-methoxyethylamino)pent-3-en-2-one, Hmeap; 4-(3-methoxypropylamino)pent-3-en-2-one, Hmpap; 4-(2-(dimethylamino)ethylamino)pent-3-en-2-one, Hdeap; 4-(3-(dimethylamino)propylamino)pent-3-en-2-one, Hdpap) leads to an amine substitution ...

The groundmass of lamproites from Middle Table Mountain, Leucite Hills, Wyoming, is characterized by the presence of potassium zirconium silicates and Sr{e-rich perovskite. Two intimately intergrown K-Z silicates of differing Ti content are recognizable by cathodoluminescence t chniques. Both are similar in composition to wadeite. Intergrown with these minerals is a phase having the composition...

The parameters for efficient nitric acid leaching were experimentally determined, which ensured the recoveries of Zr and REEs from eudialyte concentrate up to 87.0%–91.7% 76.0%–81.1%, respectively. possibility was shown intensifying process through preliminary energy treatments ensure intensive breakdown mineral complexes grains; as a result, recovery increased by more than 10%. A developed sel...

The purpose of this study was to compare the fracture resistance and fracture mode of single implant-zirconium coping combinations using zirconium and titanium abutments and to analyze the stress distribution pattern using three-dimensional finite elements analysis. Twenty implants with titanium and zirconium abutments were randomly divided into two groups (n = 10) and into resin blocks. Zircon...

Aim: The aim of this in vitro study was to evaluate imaging artifacts induced by Titanium, Zirconium, Titanium-Zirconium abutments in CT, MRI and CBCT imaging modalities.Methods: A 4×8mm titanium fixture was inserted in a dry human mandible. Titanium, Zirconium and Titanium–Zirconium abutments measuring 10.5 mm in height are located on the fixture, one by one. Each abutment was scan...

The structure of solid zirconium tetrachloride is known from X-ray studies[l] to consist of extended chains of distorted octahedra with two bridging chlorine atoms between adjacent zirconium atoms. Although the unit cell possesses a center of symmetry, the two pairs of bridging chlorine atoms attached to a given zirconium atom are not trans to each other. The factor group symmetry thus is C2h w...

Amang Zircon Sand from Onn Sdn. Bhd. mineral company has a high composition of zirconium at 61.63 wt% and low silicon 4.90 wt%. The in zircon sand indicates the possibility to synthesise it into zirconia. Zirconium was synthesised using alkali fusion method with different ratio NaOH/ZrSiO4 determine optimum based on yield. Alkali is coupled thermal treatment as will produce higher yield lower i...

UNLABELLED Indoor surfaces have a sorptive capacity for organic pollutants which may be significantly influenced by other gases and the pH of the surface. In this research, we examine the influence of a common indoor gaseous acid, CO2, and base, NH3, on the adsorption of a volatile organic base, trimethylamine (TMA), to a mineral surface, zirconium silicate beads. Varying ammonia and CO2 within...

We already reported that an intramolecular benzylation of the imino moiety of bidentate iminopyrrolyl ligands afforded an amido-pyrrolyl complexes 1 and they exhibited better catalytic activity for ethylene polymerization compared to the corresponding bis(iminopyrrolyl) dichloro complexes of zirconium. In this contribution, we prepared amido-pyrrolyl complexes of zirconium (3a-d) and hafnium (4...

IMPORTANCE Hyperkalemia is a common electrolyte abnormality that may be difficult to manage because of a lack of effective therapies. Sodium zirconium cyclosilicate is a nonabsorbed cation exchanger that selectively binds potassium in the intestine. OBJECTIVE To evaluate the efficacy and safety of zirconium cyclosilicate for 28 days in patients with hyperkalemia. DESIGN, SETTING, AND PARTIC...