Zirconium oxy-salts were hydrolyzed to form positively charged polymer or cluster species in acidic solutions. The zirconium hydrolyzed polymer was found to react with a negatively charged polyelectrolyte, such as poly(vinyl sulfate), and to form a stoichiometric polyion complex. Thus, colloidal titration with poly(vinyl sulfate) was applied to measure the zirconium concentration in an acidic s...

o bjectives: providing reliable attachment between bracket base and zirconia surface is a prerequisite for exertion of orthodontic force. the purpose of the present study was to eval- uate the effect of four zirconium surface treatment methods on shear bond strength (sbs) of orthodontic brackets. mat erials and methods: one block of zirconium was trimmed into four zirconium sur- faces, which se...

In the present study, novel MRI compatible zirconium-ruthenium alloys with ultralow magnetic susceptibility were developed for biomedical and therapeutic devices under MRI diagnostics environments. The results demonstrated that alloying with ruthenium into pure zirconium would significantly increase the strength and hardness properties. The corrosion resistance of zirconium-ruthenium alloys inc...

BACKGROUND In vitro analysis has shown that oxidized zirconium on ultra-high molecular weight polyethylene has better wear properties than cobalt-chromium on ultra-high molecular weight polyethylene. The purpose of this study was to determine if oxidized zirconium femoral components performed better than cobalt-chromium in vivo and if the use of oxidized zirconium components had clinical advers...

Reaction of a zinc/zirconium heterobimetallic complex with 1,5-cyclooctadiene (1,5-COD) results in slow isomerization to 1,3-cyclooctadiene (1,3-COD), along with the formation of a new complex that includes a cyclooctyne ligand bridging two metal centers. While analogous magnesium/zirconium and aluminum/zirconium heterobimetallic complexes are competent for the catalytic isomerization of 1,5-CO...

Sodium borohydride or sodium tetrahydroborate is used as a reducing agent in many organic and inorganic reactions. Therefore, the determination of sodium borohydride present in the system is of great importance. Borohydride releases hydrogen under appropriated conditions in the presence of a suitable catalyst. Since the amount of hydrogen emitted is proportional to the amount of borohydride, th...

Treatment of tetrakis(diethylamido)zirconium(IV); [Zr(NEt2)4] with a series of β-ketoimines ({[RHN]C(CH3)=C(H)C(CH3)=O} where R is a functionalized side-chain; 4-(2-methoxyethylamino)pent-3-en-2-one, Hmeap; 4-(3-methoxypropylamino)pent-3-en-2-one, Hmpap; 4-(2-(dimethylamino)ethylamino)pent-3-en-2-one, Hdeap; 4-(3-(dimethylamino)propylamino)pent-3-en-2-one, Hdpap) leads to an amine substitution ...

Background: Some Particular areas contain natural radionuclide at levels much higher than those usually present in earth's crust. The radiological impact of the use of zirconium ore in zirconium industry is due to internal exposure of the lung by alpha particles and external exposure of the body by the gamma rays. The result of gamma spectrometry measurement of the concentrations of th...